Synergistic extraction of Nd(III) with mixture of 8-hydroxyquinoline and its derivative with di-2-ethyl hexyl phosphoric acid in different diluents

Sutanuka Roy; Sukalyan Basu; Mallavarapu Anitha; Dhruva Kumar Singh

Korean Journal of Chemical Engineering, Vol.34, No.6, 1740-1747, June, 2017

DOI10.1007/s11814-017-0050-0 Export Citation

Synergistic extraction of Nd(III) with mixture of 8-hydroxyquinoline and its derivative with di-2-ethyl hexyl phosphoric acid in different diluents

Sutanuka Roy, Sukalyan Basu, Mallavarapu Anitha¹, and Dhruva Kumar Singh^{1, †}

Department of Chemistry, The University of Burdwan, Burdwan- 713104, India
¹Rare Earths Development Section, Materials Group, Bhabha Atomic Research Centre, Mumbai- 400085, India

E-mail:

Solvent extraction of neodymium (III) from chloride medium with synergistic mixture of 8-hydroxyquinoline or 2-methyl-8-hydroxyquinoline and di-2-ethyl hexyl phosphoric acid was investigated in different diluents. Effect of various experimental parameters such as pH, extractant concentration, diluents and temperature was studied. Role of diluents on extraction of neodymium is explained in terms of activity coefficient adopting Hildebrand regular solution theory. The negative value of enthalpy change suggests that the extraction of ternary system is exothermic. The IR data for the extracted species also substantiated the nature of extracted species as observed by slope analysis method.

Keywords:Neodymium;Synergistic Extraction;D2EHPA;8-Hydroxyquinoline;Diluent;Ternary Extraction

[References]

Zepf V, in Rare earth elements: A new approach to the nexus of supply demand and use: exemplified along the use of neodymium in permanent magnets, Springer, Berlin (2013).
Bauer D, Diamond D, Li J, Sandalow D, Telleen P, Technical Report: U.S. Department of Energy Critical Materials Strategy, December (2011).
Thakur NV, Jayawant DV, Iyer NS, Koppiker KS, Hydrometallurgy, 34(1), 99 (1993)
El-Nadi YA, Hydrometallurgy, 119-120, 23 (2012)
Lee MS, Lee JY, Kim JS, Lee GS, Sep. Purif. Technol., 46(1-2), 72 (2005)
Sato T, Hydrometallurgy, 22(1-2), 121 (1989)
Panda N, Devi N, Mishra S, J. Rare Earths, 30(8), 794 (2012)
Anitha M, Kotekar MK, Singh DK, Sharma JN, Singh H, Sep. Sci. Technol., 50(3), 430 (2015)
Deepika P, Sabharwal KN, Srinivasan TG, Vasudeva PR, Solvent Extr. Ion Exch., 28(2), 184 (2010)
Zhu Z, Sasaki Y, Suzuki H, Suzuki S, Kimura T, Anal. Chim. Acta, 527(2), 163 (2004)
Riano S, Binnemans K, Green Chem., 17, 2931 (2015)
Rout A, Binnemans K, Ind. Eng. Chem. Res., 53(15), 6500 (2014)
Dupont D, Binnemans K, Green Chem., 17, 2150 (2015)
Yoon HS, Kim CZ, Chung KW, Kim SD, Lee JY, Kumar JR, Hydrometallurgy, 165, 27 (2016)
Kumar BN, Reddy BR, Kantam ML, Kumar JR, Lee JY, Sep. Sci. Technol., 49(1), 130 (2014)
Benguerel E, Demopoulos GP, Cote D, Bauer GD, Solvent. Extr. Ion Exch, 12(3), 497 (1994)
Culp JH, Windham RL, Whealy RD, Anal. Chem., 43(10), 1321 (1971)
Sato T, Oishi H, Hydrometallurgy, 16(3), 315 (1986)
Tian M, Jia Q, Liao W, J. Rare Earths, 31(6), 604 (2013)
Tian M, Song N, Wang D, Quan X, Jia Q, Liao W, Li L, Hydrometallurgy, 109, 111 (2012)
Wu D, Zhang Q, Bao B, Hydrometallurgy, 88, 210 (2007)
Czakis-Sulikowska D, Pustelnik N, Kuznik B, Malinowska A, J. Alloy. Compd., 300-301, 234 (2000)
Shigeru T, Henry F, Solvent Extr. Ion Exch., 4(6), 1139 (1986)
Petrova MA, Lachkova VI, Vassilev NG, Varbanov SG, Ind. Eng. Chem. Res., 49(13), 6189 (2010)
Hildebrand JH, Scott RL, Solubility of non-electrolytes, Dover publications, New York (1964).
Taube M, Siekierski S, Nucleonika, 6, 489 (1961)
Singh DK, Kotekar MK, Singh H, Desalination, 232(1-3), 49 (2008)
Guezzen B, Didi MA, Int. J. Chem., 4(3), 32 (2012)
Bhar T, Banerjee M, Basu S, J. Indian Chem. Soc., 91, 1047 (2014)
Akiba K, Wada M, Kanno T, J. Inorg. Nucl. Chem., 43(5), 1031 (1981)
Choppin GR, Morgenstern A, Solvent Extr. Ion Exch., 18(6), 1029 (2000)
Anitha M, Kotekar MK, Singh DK, Vijayalakshmi R, Singh H, Hydrometallurgy, 146, 128 (2014)

[Referenced By]

[1] Zepf V, in Rare earth elements: A new approach to the nexus of supply demand and use: exemplified along the use of neodymium in permanent magnets, Springer, Berlin (2013).

[2] Bauer D, Diamond D, Li J, Sandalow D, Telleen P, Technical Report: U.S. Department of Energy Critical Materials Strategy, December (2011).

[3] Thakur NV, Jayawant DV, Iyer NS, Koppiker KS, Hydrometallurgy, 34(1), 99 (1993)

[4] El-Nadi YA, Hydrometallurgy, 119-120, 23 (2012)

[5] Lee MS, Lee JY, Kim JS, Lee GS, Sep. Purif. Technol., 46(1-2), 72 (2005)

[6] Sato T, Hydrometallurgy, 22(1-2), 121 (1989)

[7] Panda N, Devi N, Mishra S, J. Rare Earths, 30(8), 794 (2012)

[8] Anitha M, Kotekar MK, Singh DK, Sharma JN, Singh H, Sep. Sci. Technol., 50(3), 430 (2015)

[9] Deepika P, Sabharwal KN, Srinivasan TG, Vasudeva PR, Solvent Extr. Ion Exch., 28(2), 184 (2010)

[10] Zhu Z, Sasaki Y, Suzuki H, Suzuki S, Kimura T, Anal. Chim. Acta, 527(2), 163 (2004)

[11] Riano S, Binnemans K, Green Chem., 17, 2931 (2015)

[12] Rout A, Binnemans K, Ind. Eng. Chem. Res., 53(15), 6500 (2014)

[13] Dupont D, Binnemans K, Green Chem., 17, 2150 (2015)

[14] Yoon HS, Kim CZ, Chung KW, Kim SD, Lee JY, Kumar JR, Hydrometallurgy, 165, 27 (2016)

[15] Kumar BN, Reddy BR, Kantam ML, Kumar JR, Lee JY, Sep. Sci. Technol., 49(1), 130 (2014)

[16] Benguerel E, Demopoulos GP, Cote D, Bauer GD, Solvent. Extr. Ion Exch, 12(3), 497 (1994)

[17] Culp JH, Windham RL, Whealy RD, Anal. Chem., 43(10), 1321 (1971)

[18] Sato T, Oishi H, Hydrometallurgy, 16(3), 315 (1986)

[19] Tian M, Jia Q, Liao W, J. Rare Earths, 31(6), 604 (2013)

[20] Tian M, Song N, Wang D, Quan X, Jia Q, Liao W, Li L, Hydrometallurgy, 109, 111 (2012)

[21] Wu D, Zhang Q, Bao B, Hydrometallurgy, 88, 210 (2007)

[22] Czakis-Sulikowska D, Pustelnik N, Kuznik B, Malinowska A, J. Alloy. Compd., 300-301, 234 (2000)

[23] Shigeru T, Henry F, Solvent Extr. Ion Exch., 4(6), 1139 (1986)

[24] Petrova MA, Lachkova VI, Vassilev NG, Varbanov SG, Ind. Eng. Chem. Res., 49(13), 6189 (2010)

[25] Hildebrand JH, Scott RL, Solubility of non-electrolytes, Dover publications, New York (1964).

[26] Taube M, Siekierski S, Nucleonika, 6, 489 (1961)

[27] Singh DK, Kotekar MK, Singh H, Desalination, 232(1-3), 49 (2008)

[28] Guezzen B, Didi MA, Int. J. Chem., 4(3), 32 (2012)

[29] Bhar T, Banerjee M, Basu S, J. Indian Chem. Soc., 91, 1047 (2014)

[30] Akiba K, Wada M, Kanno T, J. Inorg. Nucl. Chem., 43(5), 1031 (1981)

[31] Choppin GR, Morgenstern A, Solvent Extr. Ion Exch., 18(6), 1029 (2000)

[32] Anitha M, Kotekar MK, Singh DK, Vijayalakshmi R, Singh H, Hydrometallurgy, 146, 128 (2014)