화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.34, No.6, 1867-1873, June, 2017
Study on adsorption characteristics of biochar on heavy metals in soil
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Three kinds of biochars (called poplar branch biochar (PBC), water hyacinth biochar (WHC), and corn straw biochar (CSC)) were prepared in a fixed-bed pyrolyzer at different pyrolysis temperature of 300-700 °C. The effects of biochar species, pyrolysis temperature and biochar addition on adsorption characteristics of typical heavy metals (HMs) of Pb and Zn in vegetable soil (collected from lead-zinc-silver mining area, Nanjing, China) were investigated. The obtained results indicate that WHC presents the best adsorption ability at the same experimental conditions, whose adsorption efficiency on HMs of Zn and Pb is 21.83% and 44.57%, and the relative adsorption capacity of Zn and Pb is 227.65 μg/g and 363.76 μg/g, respectively. The adsorption efficiency of biochar on HMs of Zn and Pb in soil increases gradually with the increasing of pyrolysis temperature. The increasing of biochar addition is beneficial to increase adsorption efficiency of soil HMs, but unhelpful for adsorption capacity.
  1. Rotting TS, Mercado M, Garcia ME, Quintanilla J, Int. J. Environ. Sci. Technol., 11, 935 (2014)
  2. Melo LCA, Puga AP, Coscione AR, Beesley L, Abreu CA, Camargo OA, J. Soils Sediments, 16, 226 (2016)
  3. Clemente R, Pardo T, Madejon P, Madejon E, Bernal MP, Food Res. Int., 73, 176 (2015)
  4. Lone AH, Najar GR, Ganie MA, Sofi JA, Ali T, Pedosphere, 25, 639 (2015)
  5. Colla TS, Andreazza R, Bucker F, Souza MM, Tramontini L, Prado GR, Frazzon APG, Camargo FAO, Bento FM, Environ. Sci. Pollut. Res., 21, 2592 (2014)
  6. Xu R, Zhao A, Environ. Sci. Pollut. Res., 20, 8491 (2013)
  7. Lu K, Yang X, Shen J, Robinson B, Huang H, Liu D, Bolan N, Pei J, Wang H, Agric. Ecosyst. Environ., 191, 124 (2014)
  8. Ding W, Dong X, Ime IM, Gao B, Ma LQ, Chemosphere, 105, 68 (2014)
  9. Li M, Du L, Zhang Y, Gao Y, J. Soil Water Conserv., 27, 261 (2013)
  10. Beesley L, Moreno-Jimenez E, Gomez-Eyles JL, Harris E, Robinson B, Sizmur T, Environ. Pollut., 159, 3269 (2011)
  11. Li D, Hockaday WC, Masiello CA, Alvarez PJJ, Soil Biology Biochem., 43, 1732 (2011)
  12. Liu J, Yang X, Lu K, Zhang X, Huang H, Wang H, Acta Scientiae Circumstantiae, 35, 3679 (2015)
  13. Jiang T, Jiang J, Xu R, Li Z, Chemosphere, 89, 249 (2012)
  14. Sun K, Gao B, Ro KS, Novak JM, Wang Z, Herbert S, Xing B, Environ. Pollut., 163, 167 (2012)
  15. Song Y, Wang F, Bian YR, Kengara FO, Jia MY, Xie ZB, Jiang X, J. Hazard. Mater., 217, 391 (2012)
  16. Moon DH, Park J, Chang Y, Ok YS, Lee SS, Ahmad M, Koutsospyros A, Park J, Baek K, Environ. Sci. Pollut. Res., 20, 8464 (2013)
  17. Houben D, Evrard L, Sonnet P, Biomass Bioenerg., 57, 196 (2013)
  18. Choi JH, Kim SS, Suh DJ, Jang EJ, Min KI, Woo HC, Korean J. Chem. Eng., 33(9), 2691 (2016)
  19. Shu T, Lu P, He N, Bioresour. Technol., 136, 182 (2013)
  20. Li F, Bade R, Oh S, Shin WS, Korean J. Chem. Eng., 29(10), 1362 (2012)
  21. China MEP. GB15618-2008: Environmental quality standards for soils, Beijing, China (2008).
  22. Park JH, Yong SO, Kim SH, Chemosphere, 142 (2016).
  23. Chen XC, Chen GC, Chen LG, Chen YX, Lehmann J, McBride MB, Hay AG, Bioresour. Technol., 102(19), 8877 (2011)
  24. Ahmad M, Rajapaksha AU, Lim JE, Zhang M, Bolan N, Mohan D, Vithanage M, Lee SS, Ok YS, Chemosphere, 99, 19 (2014)
  25. Ding W, Zhu Q, Zeng X, Tian X, Sci. Technol. Review, 29, 22 (2011)
  26. Li G, Zhu W, Zhu L, Chai X, Korean J. Chem. Eng., 33(7), 2215 (2016)
  27. Ni L, Weng R, J. Environ. Eng. Technol., 5, 59 (2015)