Journal of Industrial and Engineering Chemistry, Vol.51, 153-161, July, 2017
Study on the effect of current collector structures on the performance of MCFCs using three-dimensional fluid dynamics analysis
E-mail:,
The effect of current collectors of molten carbonate fuel cells (MCFCs) was studied through threedimensional computational fluid dynamics and experiments. Three types of current collectors such as a sheet with sheared protrusions and perforated sheets were employed and performances of MCFCs were compared. A current collector structure with a large gas open area to electrodes improves diffusion characteristics between electrodes and gas flow channels. As a result, differences of gas mole fractions between gas flow channels and electrodes were decreased. Finally, Nernst loss and cathode polarization loss decreased, and the performance was enhanced. Using these results, current collector structures for improved performance and long-term operation were discussed.
- Li X, Principles of Fuel Cells, Taylor & Francis Group, New York, 2005.
- Choi BH, Sung HJ, Int. J. Hydrog. Energy, 39(24), 12913 (2014)
- Li XG, Sabir M, Int. J. Hydrog. Energy, 30(4), 359 (2005)
- Yang WM, Chou SK, Shu C, J. Power Sources, 164(2), 549 (2007)
- Chen R, Zhao TS, Electrochim. Acta, 52(13), 4317 (2007)
- Yan XH, Zhao TS, An L, Zhao G, Zeng L, Electrochim. Acta, 139, 7 (2014)
- Shimpalee S, Greenway S, Van Zee JW, J. Power Sources, 160(1), 398 (2006)
- Shimpalee S, Van Zee JW, Int. J. Hydrog. Energy, 32(7), 842 (2007)
- Wang JY, Appl. Energy, 157, 640 (2015)
- Ghanbarian A, Kermani MJ, Energy Conv. Manag., 110, 356 (2016)
- Hirata H, Nakagaki T, Hori M, J. Power Sources, 83(1-2), 41 (1999)
- Yoshiba F, Ono N, Izaki Y, Watanabe T, Abe T, J. Power Sources, 71(1-2), 328 (1998)
- Ma Z, Jeter SM, Abdel-Khalik SI, Int. J. Hydrog. Energy, 28(1), 85 (2003)
- Kim H, Bae J, Choi D, Int. J. Hydrog. Energy, 38(11), 4782 (2013)
- Kim YJ, Chang IG, Lee TW, Chung MK, Fuel, 89(5), 1019 (2010)
- Koh JH, Kang BS, Int. J. Energy Res., 25(7), 621 (2001)
- Yoshiba F, Int. J. Energy Res., 28(15), 1361 (2004)
- Lee CW, Lee M, Lee MJ, Chang SC, Yoon SP, Ham HC, Han J, Int. J. Hydrog. Energy, 41(41), 18747 (2016)
- Vielstich W, Lamm A, Gasteiger HA, Handbook of fuel cells: fundamentals technology and applications, Fuel Cell Technology and Applications, vol. 4, Wiley, 2003.
- Lee CW, Yang DY, Kang DW, Lee TW, Int. J. Hydrog. Energy, 39(12), 6714 (2014)
- Koh JH, Kang BS, Lim HC, J. Power Sources, 91(2), 161 (2000)
- Yuh C, Selman J, J. Electrochem. Soc., 138, 3642 (1991)
- Brouwer J, Jabbari F, Leal EM, Orr T, J. Power Sources, 158(1), 213 (2006)
- Koh JH, Seo HK, Yoo YS, Lim HC, Chem. Eng. J., 87(3), 367 (2002)
- Verda V, Sciacovelli A, Appl. Therm. Eng., 31, 2740 (2011)
- Blomen LJ, Mugerwa MN, Fuel Cell Systems, Springer Science & Business Media, 2013.
- Baranak M, Atakul H, J. Power Sources, 172(2), 831 (2007)
- COMSOL Multiphysics v4.2, COMSOL Inc., 2014.
- Goswami DY, Kreith F, Handbook of Energy Efficiency and Renewable Energy, Crc Press, 2007.
- Nguyen HVP, Kang MG, Ham HC, Choi SH, Han J, Nam SW, Hong SA, Yoon SP, J. Electrochem. Soc., 161(14), F1458 (2014)
- Yuh C, Colpetzer J, Dickson K, Farooque M, Xu G, J. Mater. Eng. Perform., 15, 457 (2006)
- Hoang VPN, Song SA, Park DN, Ham HC, Han J, Yoon SP, Othman MR, Kim J, Int. J. Hydrog. Energy, 37(21), 16161 (2012)