Effect of crosslinking agents on the dispersive behaviour of polymer particles in seed swelling polymerisation

Yu-Chen Kao; Wha-Tzong Whang; Yi-Chun Chen; Kai-Chi Chen

Journal of Industrial and Engineering Chemistry, Vol.51, 216-222, July, 2017

DOI10.1016/j.jiec.2017.03.003 Export Citation

Effect of crosslinking agents on the dispersive behaviour of polymer particles in seed swelling polymerisation

Yu-Chen Kao^†, Wha-Tzong Whang, Yi-Chun Chen¹, and Kai-Chi Chen¹

Department of Material Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan
¹Department of Material and Chemical Research Laboratories, Industrial Technology Research Institute, Hsinchu, Taiwan

E-mail:

This study focused on the effect of crosslinker structure between PMMA on the dispersity of crosslinked particles in seed swelling polymerisation. We used five different crosslinking agents in an assessment of the dispersity of crosslinking monodisperse particles using PMMA seed particles in seed swelling polymerisation. These results show that the structure of the crosslinking agent affects the dispersity during the swelling stage. According to the solubility parameter theory of computation, the departure of similar solubility parameter causes the swollen particles to segregate into more dispersity.

Keywords:Dispersity;Crosslinking agent;Solubility parameter;Methyl group;Seed swelling polymerisation

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Jiang S, Sudol ED, Dimonie VL, El-Aasser MS, J. Appl. Polym. Sci., 107(4), 2453 (2008)
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Ugelstad J, Kaggerud KH, Hansen FK, Berge A, Macromol. Chem. Phys., 180, 737 (1979)
Yamashita T, Okubo M, Colloid Polym. Sci., 275, 214 (1997)
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Zhang Q, Han Y, Wang WC, Song T, Chang J, J. Colloid Interface Sci., 342(1), 62 (2010)
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Okubo M, Ise E, Yamashita T, J. Polym. Sci. A: Polym. Chem., 36(14), 2513 (1998)
Okubo M, Yamashita T, Shiozaki M, J. Appl. Polym. Sci., 60(7), 1025 (1996)
Zohrehvand S, Polym. Int., 54, 1191 (2005)
Kim JW, Suh KD, Polymer, 41(16), 6181 (2000)
Kim DH, Lee DY, Lee KS, Choe SJ, Macromol. Res., 17(4), 250 (2009)
Kim DO, Jin JH, J. Appl. Polym. Sci., 105(2), 783 (2007)
Rajendran S, Uma T, Mater. Lett., 44, 242 (2000)
Rajendran S, Uma T, J. Power Sources, 88(2), 282 (2000)
Chaiyasat P, Chaiyasat A, Boontung W, Promdsorn S, Thipsit S, Mater. Sci. Appl., 2, 1007 (2011)

[1] Lok KP, Ober CK, Can. J. Chem., 63, 209 (1985)

[2] Kim OH, Lee K, Kim K, Lee BH, Choe S, Polymer, 47(6), 1953 (2006)

[3] Jiang S, Sudol ED, Dimonie VL, El-Aasser MS, J. Appl. Polym. Sci., 107(4), 2453 (2008)

[4] Shen S, Sudol ED, El-aasser MS, J. Polym. Sci. A: Polym. Chem., 31, 1393 (1993)

[5] Nagao D, Sakamoto T, Konno H, Gu SC, Konno M, Langmuir, 22(26), 10958 (2006)

[6] Can S, Tanrisever T, J. Appl. Polym. Sci., 103(4), 2494 (2007)

[7] Dowding PJ, Vincent B, Colloids Surf. A: Physicochem. Eng. Asp., 161, 259 (2000)

[8] Gong T, Wang CC, J. Mater. Sci., 43(6), 1926 (2008)

[9] Thomson B, Rudin A, Lajoie G, J. Appl. Polym. Sci., 59(13), 2009 (1996)

[10] Song JS, Winnik MA, Macromolecules, 38(20), 8300 (2005)

[11] Ugelstad J, Kaggerud KH, Hansen FK, Berge A, Macromol. Chem. Phys., 180, 737 (1979)

[12] Yamashita T, Okubo M, Colloid Polym. Sci., 275, 214 (1997)

[13] Okubo M, Hosotani T, Yamashita T, Izumi J, Colloid Polym. Sci., 275, 888 (1997)

[14] Zhang Q, Han Y, Wang WC, Song T, Chang J, J. Colloid Interface Sci., 342(1), 62 (2010)

[15] Kim JW, Suh KD, J. Ind. Eng. Chem., 14(1), 1 (2008)

[16] Yang W, Ming W, Hu J, Lu X, Fu S, Colloid Polym. Sci., 276, 655 (1998)

[17] Okubo M, Ise E, Yamashita T, J. Polym. Sci. A: Polym. Chem., 36(14), 2513 (1998)

[18] Okubo M, Yamashita T, Shiozaki M, J. Appl. Polym. Sci., 60(7), 1025 (1996)

[19] Zohrehvand S, Polym. Int., 54, 1191 (2005)

[20] Kim JW, Suh KD, Polymer, 41(16), 6181 (2000)

[21] Kim DH, Lee DY, Lee KS, Choe SJ, Macromol. Res., 17(4), 250 (2009)

[22] Kim DO, Jin JH, J. Appl. Polym. Sci., 105(2), 783 (2007)

[23] Rajendran S, Uma T, Mater. Lett., 44, 242 (2000)

[24] Rajendran S, Uma T, J. Power Sources, 88(2), 282 (2000)

[25] Chaiyasat P, Chaiyasat A, Boontung W, Promdsorn S, Thipsit S, Mater. Sci. Appl., 2, 1007 (2011)