화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.8, 2154-2161, August, 2017
DOI10.1007/s11814-017-0122-1  Export Citation
UV-LEDs assisted peroxymonosulfate/Fe2+ for oxidative removal of carmoisine: The effect of chloride ion
Mehdi Ahmadi1, 2, Farshid Ghanbari3, †, Alberto Alvarez4, and Susana Silva Martinez4
  • 1Environmental Technologies Research Center, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
  • 2Department of Environmental Health Engineering, School of Public Health, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
  • 3Student Research Committee, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
  • 4Centro de Investigación en Ingeniería y Ciencias Aplicadas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Col. Chamilpa, Cuernavaca, Mor. Mexico. C.P. 62209, Mexico
E-mail:
The performance of UVA-LEDs assisted peroxymonosulfate (PMS)/Fe2+ system was evaluated on carmoisine (E122) decolorization. Complete color removal was obtained under the conditions of pH=3.0, PMS=1.5mM, Fe2+=1mM and 25 min reaction time. UVA-LEDs were preferable compared to conventional UVA lamp in terms of decolorization. The functions of Co2+, Cu2+, Mn2+ and Fe2+ were compared and their results showed that Co2+ and Fe2+ had the highest efficiencies. Moreover, the presence of chloride ion showed a double role in different concentrations in which promotional effect was observed in 100mM Cl-<, while inhibitory effect occurred in 1-10mM Cl-. However, the high concentration of chloride had no influence on mineralization of E122. The scavenging results demonstrated that the UV irradiation increased the contribution of HO°. In addition, in the presence of chloride ion, HOCl along with sulfate and hydroxyl radicals were the major oxidative agents.
Keywords:Food Dye;UVA-LEDs;Sulfate Radical;Peroxymonosulfate;Scavenging Effect
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