화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.8, 2311-2324, August, 2017
DOI10.1007/s11814-017-0086-1  Export Citation
Decreasing ICP of forward osmosis (TFN-FO) membrane through modifying PES-Fe3O4 nanocomposite substrate
Rezvaneh Ramezani Darabi, Majid Peyravi, Mohsen Jahanshahi†, and Ali Asghar Qhoreyshi Amiri
  • Nanotechnology Institute, Faculty of Chemical Engineering, Babol Noshirvani University of Technology, Babol, Iran
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This film nanocomposite forward osmosis (TFN-FO) membrane was developed using polyethersulfone-ferrous ferric oxide (PES-Fe3O4) nanocomposite substrate. The results revealed that the porosity and the hydrophilicity of the PES substrate were improved after addition of Fe3O4 nanoparticles (NPs), leading to reducing in structural parameter (S value or S) and water flux enhancement. To fabricate TFN membranes for FO application, a thin polyamide layer was fabricated by interfacial polymerization of m-Phenylenediamine (MPD) and 1, 3, 5-trimesoylchloride (TMC) on the top surface of PES-Fe3O4 nanocomposite substrates. The TFN membrane prepared with 0.2 wt% Fe3O4 NPs showing the most reliable results by exhibiting high water flux and low reverse solute flux. Furthermore, TFN0.2 membrane exhibited significantly higher pure water flux than that of control thin film composite (TFC) membrane in both AL-FS and AL-DS orientation when 10 mM NaCl and Caspian seawater was used as feed solution and 0.5 or 2M NaCl was used as draw solution. This improvement can be attributed to the fact that the S value of TFN0.2 is much lower in comparison to control TFC membrane (0.42 vs 0.78 mm), leading to reduced internal concentration polarization (ICP) effect.
Keywords:Internal Concentration Polarization;Fe3O4 Nanoparticle;Thin Film Nanocomposite Substrate;Forward Osmosis
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