화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.25, No.7, 671-679, July, 2017
DOI10.1007/s13233-017-5065-1  Export Citation
Magnetite Loaded Cross-linked Polystyrene Composite Particles Prepared by Modified Suspension Polymerization and Their Potential Use as Adsorbent for Arsenic(III)
Hasan Ahmad†, Mostafa Kaiyum Sharafat, Mohammad Ashraful Alam, Mohammad Mahbubor Rahman, Klaus Tauer1, Hideto Minami2, Mosammat Sharmin Sultana, Basudev Kumar Das, and Rukhsana Shabnam
  • Department of Chemistry, Rajshahi University, Rajshahi 6205, Bangladesh, Korea
  • 1Max Planck Institute of Colloid and Interfaces, Am Mühlenberg, 14476 Golm, Germany
  • 2Graduate School of Engineering, Kobe University, Kobe 657-8501, Japan
E-mail:
Magnetic particles have attracted much interest because they can be easily guided under the influence of magnetic field and are considered suitable in biomedical as well as in separation technology. In this work, magnetite (Fe3O4) loaded cross-linked polystyrene (PS) composite particles are prepared by a novel suspension polymerization of styrene and divinylbenzene (DVB) in presence of nanosized iron oxide (Fe3O4) particles dispersed in n-octane. The structure and surface properties are systematically characterized using FTIR, scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and thermogravimetric analyses (TGA). The morphology and surface structure reveal that Fe3O4 nanoparticles are mostly dispersed within the P(S-DVB) copolymer layer. Finally the applicability of Fe3O4/P(S-DVB) composite polymer particles as adsorbent for toxic element like trivalent arsenic (As) has been investigated. Fe3O4/P(S-DVB) composite polymer particles exhibited good sorption efficiency compared to reference P(S-DVB) copolymer particles.
Keywords:cross-linked polystyrene (PS) composite;Fe3O4;suspension polymerization;morphology;adsorption;arsenic(III)
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