화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 187-196, August, 2017
DOI10.1016/j.jiec.2017.03.043  Export Citation
Zeolite properties improvement by chitosan modification.Sorption studies
Dorota Kolodynska†, Paulina Halas, Malgorzata Franus1, and Zbigniew Hubicki
  • Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie Skłodowska Sq. 2, 20-031 Lublin, Poland
  • 1Department of Geotechnical Engineering, Faculty of Civil Engineering and Architecture, Nadbystrzycka 40, 20-618 Lublin, Poland
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In the paper the potential of chitosan modified zeolite (NaP1CS) as a cheap adsorbent for methylene blue (MB) removal from aqueous solutions was determined. Fourier transform infrared spectroscopy analyses, nitrogen adsorption/desorption isotherms and scanning electron microscope were applied to characterize the adsorbent. Batch adsorption studies were carried out to examine effects of various factors such as pH, contact time, initial MB and Cu(II) concentrations, temperature influence on the sorption process. The impact of different ways of zeolites modification with chitosan on sorption capacity and the comparison of adsorption of unmodified zeolite and fly ash are presented. The effect of different metal ions such as Cu(II), Zn(II), Mn(II), Fe(III) and also that of foreign ions on the MB sorption were also studied. The pseudo-first order, pseudo-second order and intraparticle diffusion models were fitted to the kinetic data. The best fit was achieved with both the pseudo-second order and intraparticle diffusion models. The experimental equilibrium data were evaluated by the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. The calculated thermodynamic parameters indicated a spontaneous and endothermic sorption process. Desorption studies were carried out with different desorbing agents. HCl proved to be the most effective desorption agent for MB and Cu(II).
Keywords:Fly ash;Zeolite;Chitosan;Dyes;Modification
  1. Li C, Zhong H, Wang S, Xue J, Zhang Z, J. Ind. Eng. Chem., 23, 344 (2015)
  2. Aysan H, Edebali S, Ozdemir C, Karakaya MC, Karakaya N, Microporous Mesoporous Mater., 235, 78 (2016)
  3. Jung KW, Choi BH, Hwang MJ, Jeong TU, Ahn KU, Ahn, Bioresour. Technol., 219, 185 (2016)
  4. Peng W, Li H, Liu Y, Song S, J. Mol. Liq., 221, 82 (2016)
  5. Setiabudi HD, Jusoh R, Suhaimi SFRM, Masrur SF, J. Taiwan Inst. Chem. Eng., 63, 363 (2015)
  6. Kumar A, Jena HM, J. Clean Prod., 137, 1246 (2016)
  7. Lin S, Song Z, Che G, Ren A, Li P, Liu C, Zhang J, Microporous Mesoporous Mater., 193, 27 (2014)
  8. Zhao M, Liu P, Microporous Mesoporous Mater., 112(1-3), 419 (2008)
  9. Lin LD, Lin Y, Li CJ, Wu DY, Kong HN, Int. J. Miner. Process., 148, 32 (2016)
  10. Jia Z, Li Z, Li S, Li Y, Zhu R, J. Mol. Liq., 220, 56 (2016)
  11. Li L, Liu F, Duan H, Wang X, Li J, Wang Y, Luo C, Colloids Surf. B: Biointerfaces, 141, 253 (2016)
  12. Aluigi A, Rombaldoni F, Tonetti C, Jannoke L, J. Hazard. Mater., 268, 156 (2014)
  13. Qi JQ, Li XC, Zheng H, Li PQ, Wang HY, J. Hazard. Mater., 293, 105 (2015)
  14. Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
  15. Ali RM, Hamad HA, Hussein MM, Malash GF, Ecol. Eng., 91, 317 (2016)
  16. Pimentel PM, Melo MAF, Melo DMA, Assuncao ALC, Henrique DM, Silva CN, Gonzalez G, Fuel Process. Technol., 89(1), 62 (2008)
  17. Constantin M, Asmarandei I, Harabagiu V, Ghimici L, Ascenzi P, Fundueanu G, Carbohydr. Polym., 91(1), 74 (2013)
  18. Luo X, Zhang Z, Zhou P, Liu Y, Ma G, Lei Z, J. Ind. Eng. Chem., 27, 164 (2015)
  19. Erdem E, Karapinar N, Donat R, J. Colloid Interface Sci., 280(2), 309 (2004)
  20. Visa M, Chelaru AM, Appl. Surf. Sci., 303, 14 (2014)
  21. Franus W, Wiatros-Motyka MM, Wdowin M, Environ. Sci. Pollut. Res., 22(12), 9464 (2015)
  22. Atun G, Hisarli G, Kurtoglu AE, Ayar N, J. Hazard. Mater., 187(1-3), 562 (2011)
  23. Visa M, Powder Technol., 294, 338 (2016)
  24. Wen J, Yi Y, Zeng G, J. Environ. Manage., 178, 63 (2016)
  25. Li C, Zhong H, Wang S, Xue J, Zhang Z, Colloids Surf. A: Physicochem. Eng. Asp., 470, 258 (2015)
  26. Wang C, Li J, Sun X, Wang L, Sun X, J. Environ. Sci., 21(1), 127 (2009)
  27. Wang Z, Fan Y, Li Y, Qu F, Wu D, Kong H, Microporous Mesoporous Mater., 222, 226 (2016)
  28. He Y, Lin H, Dong Y, Liu Q, Wang L, Chemosphere, 164, 387 (2016)
  29. Huang H, Yang L, Xue Q, Liu J, Hou L, Ding L, J. Environ. Manage., 160, 333 (2015)
  30. Franus M, Wdowin M, Bandura L, Franus W, Fresenius Environ. Bull., 24(3A), 854 (2015)
  31. Bandura L, Franus M, Jozefaciuk G, Franus W, Fuel, 147, 100 (2015)
  32. Bandura L, Panek R, Rotko M, Franus W, Microporous Mesoporous Mater., 223, 1 (2016)
  33. Muir B, Bajda T, Fuel Process. Technol., 149, 153 (2016)
  34. Esfahani SMB, Faghihian H, J. Water Process Eng., 3(C), 62 (2014)
  35. Ngah WSW, Teong LC, Toh RH, Hanafiah MAKM, Chem. Eng. J., 209, 46 (2012)
  36. Ngah WSW, Teong LC, Toh RH, Hanafiah MAKM, Chem. Eng. J., 223, 231 (2013)
  37. Nesic AR, Velickovic SJ, Antonovic DG, Compos. B: Eng., 53, 145 (2013)
  38. Khanday WA, Asif M, Hameed BH, Int. J. Biol. Macromol., 95, 895 (2016)
  39. Purnomo CW, Salim C, Hinode H, Microporous Mesoporous Mater., 162, 6 (2012)
  40. Sanchez-Hernandez R, Lopez-Delgado A, Padilla I, Galindo R, Lopez-Andres S, Microporous Mesoporous Mater., 226, 267 (2016)
  41. Kyzas GZ, Bikiaris DN, Mar. Drugs, 13(1), 312 (2015)
  42. Abbasi A, J. Clean Prod., 145, 105 (2017)
  43. Marrakchi F, Ahmed MJ, Khanday WA, Asif M, Hameed BH, Int. J. Biol. Macromol., 98, 233 (2017)
  44. Gul K, Sohni S, Waqar M, Ahmad F, Norulaini NAN, M.O.A.K, Carbohydr. Polym., 152, 520 (2016)
  45. Cho DW, Jeon BH, Chon CM, Schwartz FW, Jeong Y, Song H, J. Ind. Eng. Chem., 28, 1 (2014)
  46. Xie J, Li CJ, Chi LA, Wu DY, Fuel, 103, 480 (2013)
  47. Guibal E, Sep. Purif. Technol., 38(1), 43 (2004)
  48. Franus W, Pol. J. Environ. Stud., 21(2), 337 (2012)
  49. Wdowin M, Franus M, Panek R, Badura L, Franus W, Clean Technol. Environ. Policy, 16, 1217 (2014)
  50. Nashine AL, Tembhurkar AR, J. Environ. Chem. Eng., 4(3), 3267 (2016)
  51. Lee KY, Park M, Kim J, Oh M, Lee EH, Kim KW, Chung DY, Moon JK, Chemosphere, 150, 765 (2016)
  52. Fierro V, Torne-Fernandez V, Montane D, Celzard A, Microporous Mesoporous Mater., 111(1-3), 276 (2008)
  53. Chung HK, Kim WH, Park J, Cho J, Jeong TY, Park PK, J. Ind. Eng. Chem., 28, 241 (2015)
  54. Coles CA, Yong RN, Eng. Geol., 85(1-2), 19 (2006)
  55. Liu X, Zhang LF, Powder Technol., 277, 112 (2015)
  56. Nebaghe KC, El Boundati Y, Ziat K, Naji A, Rghioui L, Saidi M, Fluid Phase Equilib., 430, 188 (2016)
  57. Shakoor S, Nasar A, J. Taiwan Inst. Chem. Eng., 15, 30 (2016)
  58. Valdes H, Tardon RF, Zaror CA, Chem. Eng. J., 211-212, 388 (2012)
  59. Fungaro DA, Bruno M, Grosche LC, Desalin. Water Treat., 2, 37 (2009)
  60. Weber WJ, Morris JC, J. Sanit. Eng. Division, 89(2), 31 (1963)
  61. Millar GJ, Couperthwaite SJ, Alyuz K, J. Environ. Chem. Eng., 4(2), 1918 (2016)
  62. Liu T, Li Y, Du Q, Sun J, Jiao Y, Yang G, Wang Z, Xia Y, Zhang W, Wang K, Zhu H, Wu D, Colloids Surf. B: Biointerfaces, 90(1), 197 (2012)
  63. Tseng RL, Wu FC, J. Hazard. Mater., 155(1-2), 277 (2008)
  64. Wu FC, Tseng RL, Juang RS, Chem. Eng. J., 153(1-3), 1 (2009)
  65. Ramteke LP, Gogate PR, Sep. Purif. Technol., 163, 215 (2016)
  66. Subbaiah MV, Kim DS, Ecotox. Environ. Safe., 128, 109 (2016)
  67. Gusain D, Singh PK, Sharma YC, Environ. Nanotechnol. Monit. Manage., 6, 99 (2016)