화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 349-358, August, 2017
DOI10.1016/j.jiec.2017.04.011  Export Citation
Dimer-type heterostructure of Ag/Zn0.995Ni0.005O microspheres: Microwave-assisted synthesis and synergistic antibacterial activity
Linxiang Tan1, Wenjie Wu1, 2, Qiaoqiao Yin1, Xiaoxia Ke1, Ru Qiao1, †, Guoxiu Tong1, and Lanlan Zhu1
  • 1College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China
  • 2Shandong Fiberglass Group Co., LTD., Linyi 276400, China
E-mail:
The dimer-type heterostructured Ag/Zn0.995Ni0.005O microspheres were prepared via two step microwave-assisted process, which exhibited stronger visible-light-activated antibacterial performance than visible-light only, ZnO/Vis, Zn0.995Ni0.005O/Vis, or AgNPs/Vis. It is attributed to not only the interaction of released metal ions with functional groups of vital enzymes and proteins, but also the collapsing force of reactive oxygen species to the cells. Photoelectrochemical measurements show that the photogenerated charges of Ag/Zn0.995Ni0.005O possess longer lifetime and higher separation resulting from the synergistic effect between Ni and Ag, which leads to its superior visible-light driven antibacterial performance. Gram-negative bacteria are more effectively restrained by Ag/Zn0.995Ni0.005O than Gram-positive bacteria because of structural difference between their cell walls.
Keywords:Zn1-xNixO;Ag nanoparticles;Dimer-type heterostructure;Synergistic antibacterial activity;Photoelectrochemical property
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