Applied Surface Science, Vol.411, 291-302, 2017
A travel in the Echeveria genus wettability's world
Nature is a constant source of inspiration for researchers and engineers. In this work, we study the wettability of various species from the genus Echeveria. All species studied present very strong hydrophobic properties with various water adhesions. Echeveria 'Perle von Nurnberg' has properties very close to superhydrophobicity with low water adhesion (sliding angle alpha = 15 degrees and contact angle hysteresis H = 9 degrees) while Echeveria pallida and Echeveria runyonii are completely sticky (parahydrophobic) and water droplets do not move even if the surface is inclined to 90 degrees. This work shows that most of the differences in the hydrophobic properties depend on the amount of wax crystallization. However, Echeveria pulvinata shows special wettability results. Their leaves possess long hairs. When a water droplet is placed on the surface, the water droplet is completely sticky. When the size of the droplets becomes critical, the water droplets spread across the leaf surface displaying superhydrophilic properties. More investigations reveal that the hairs are highly hydrophobic and rough due to the presence of wax crystals while the bottom of the surface is smooth and hydrophilic. Such materials are excellent candidates for water harvesting systems and oil/water separation membranes. (C) 2017 Elsevier B.V. All rights reserved.