In this work, the PtAg2/C-D and PtPd3Ag5/C-D catalysts with Pt-rich surfaces were fabricated via chemical reduction following electrochemical dealloying. The as-prepared catalysts were characterized by X-ray diffraction (XRD), transmission electron spectroscopy (TEM), atomic adsorption spectroscopy (AAS), X-ray electron spectroscopy (XPS) and electrochemical methods It is found that external Ag atoms are dealloyed by the cyclic voltammetry (CV) to expose more Pt active sites on the surface, which enhances the electrocatalytic performance greatly. The addition of Pd as another sacrificing element triggers higher activity due to the synergistic effect between Pd and Pt. The mass activity of as-prepared PtAg2/C-D catalyst reaches 3.35 times as high as that of Pt/C. The PtPd3Ag5/C-D catalyst has the highest electrocatalytic activity of 4500 mA mg(-1), which is 6.22 and 1.87 times as high as those of mono component Pt/C and Pd/C, respectively. Their high electrocatalytic activity is attributed to electronic effects, oxygen-containing species from Pd oxides and higher utilization of Pt. (C) 2017 Elsevier Ltd. All rights reserved.