Rh catalysts with low Rh content were prepared by incipient wetness impregnation using [NH4](3)[RhCl6]center dot 3H(2)O or RhCl3 center dot 3H(2)O as precursor salts, on CaO SiO2 supports. All solids showed a high stability after 48 h on stream for the dry reforming of methane with low carbon content, which made them suitable for obtaining ultrapure hydrogen in a membrane reactor. The methane conversion and hydrogen recovery were measured increasing the sweep gas flow rates to rise the driving force for hydrogen permeation. The catalyst with 0.36 wt.% of Rh showed a slight deactivation. However, the Rh(0.6)/CaO-SiO2 solid, in which the Rh impregnation was performed using [NH4](3)[RhCl6]center dot 3H(2)O, exhibited an increase on CH4 conversion of 77% and a hydrogen recovery equal to 84%. Nanoparticles of about 1.4-1.7 nm surface average diameter were detected for the reduced and used solids indicating that Rh is well dispersed and sintering was not produced after the catalytic tests. Rh particle sizes calculated by CO chemisorption were coincident with those measured by Transmission Electron Microscopy. Characterization by this technique and Laser Raman Spectroscopy of the solids used in membrane reactor revealed the formation of scarce carbon filaments. However, a surface re-oxidation was detected in the low loading catalyst used in the membrane reactor suggesting that it is the main cause for the decrease in the activity of the highly dispersed catalyst. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.