화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.42, No.24, 15908-15912, 2017
Preparation and Nc/T plots of un-crystallized Nafion 1100 and semi-crystalline Nafion 1000
The last advances on the application of INCA (Ionomer Nc Analysis) methodology for a better understanding of perfluorinated ionomers are reported and discussed. It was found that INCA is a very suitable technique for the determination of the melting temperature (Tm) of un-crystallized and semi-crystalline perfluorinated ionomers. Furthermore, for these determinations, it is even more precise than dynamic mechanical analysis, a method essentially developed for polymers in which the water-uptake is negligible. Of interest, it is the information that INCA methodology gives on the phenomenon of the water-uptake memory of perfluorinated ionomers. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.