Graphene oxide (GO) was used as an additive to the anode, to modify the electrochemical properties of polymer fuel cells (PEMFC) based on Nafion. GO was obtained by modified Hummers method and fully characterized by Raman, FTIR, X-ray, TEM, electrochemically (CV) and Surface Area and Porosity Analyzer. PEMFC with a GO-based anode containing about 30% less Pt, was constructed and compared with a cell with standard anodes. The electrodes were electrochemically tested at 25 and 60 degrees C. A maximum power density of 134 mW/cm(2) with a current density of 374 mA/cm(2) was achieved for PEMFC with GO-based anode at 60 degrees C. The electrochemical surface area (ECSA) of the PEMFC with GO-based anode was about two times higher than that of the reference device. The electrochemical characterization as well as the Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) analysis indicate that GO in the anode reduced Pt agglomeration, as a consequence of the increased surface area and decreased average pore width, compared with the reference electrode. Well-fitted equivalent circuits were proposed and discussed after an electrochemical impedance spectroscopy study of the constructed devices. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.