화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.42, No.17, 12507-12520, 2017
Development of ultra-low highly active and durable hybrid compressive platinum lattice cathode catalysts for polymer electrolyte membrane fuel cells
A highly active and stable catalyst/support system is developed by using a two-step process. In the first step, activated carbon composite support (ACCS) is synthesized that retains its activity after accelerated stress test (AST). A 30% Pt/ACCS catalyst shows no loss of mass activity and power density after 5000 cycles at 1.0-1.5 V while the commercial Pt/C and Pt/290G catalysts show drastic mass activity losses (57.5% and 66.2%, respectively) and power density losses (88.7% and 84.0%, respectively). In the second step, Pt catalyst with a compressive Pt lattice (Pt*) is synthesized through a USC-developed annealing procedure in which Co atoms previously embedded in the support diffuse into Pt. The 30% Pt*/ACCS shows high initial power density (rated) of 0.174 g(pt) kW(-1) and high stability of 24 mV loss at 0.8 A cm(-2) with an electrochemical active surface area (ECSA) loss of 42% after 30,000 cycles (0.6-1.0 V). The support stability under 1.0-1.5 V potential cycling shows potential loss of 8 mV at 1.5 A cm(-2) and ECSA loss of 22% after 5000 cycles. Improved stability and activity of Pt*/ACCS catalyst are due to synergistic effect of catalytic activity and stability of ACCS and formation of compressive Pt lattice catalyst. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.