The effect of solid oxide fuel cell cathode microstructure modification on its electrochemical activity is investigated. Inkjet printing infiltration was used to develop a nano-decoration pattern on the composite cathode scaffolds. Two types of composite La0.6Sr0.4Co0.2Fe0.8O3-delta:Ce0.9Gd0.1O1.9 cathodes with different volume ratios (60:40 and 40:60 vol%) were fabricated using inkjet printing of suspension inks. The electrodes were altered by single-step inkjet printing infiltration of ethanol-based Ce0.9Gd0.1O1.9 ink. After heat treatments in air at 550 A degrees C the cathodes' surfaces were shown to be nano-decorated with Ce0.9Gd0.1O1.9 particles (similar to 20-120 nm in size) dispersed uniformly onto the electrode scaffold. The nano-engineered microstructure enhanced the active triple phase boundary of the electrode and promoted the surface exchange reaction of oxygen. Electrochemical impedance tests conducted on symmetrical cells showed a reduction in the polarization resistance of between 1.3 and 2.9 times. The effect was found to be more pronounced in the 60:40 vol% composite cathodes. Ageing of infiltrated electrodes up to 60 h in air revealed enhanced stability of gadolinium doped ceria nanoparticles decorated electrodes ascribed to the suppression of SrO surface segregation. This work demonstrated that single-step inkjet printing infiltration can produce reproducible performance enhancements and thus offers a cost-effective route for commercial solid oxide fuel cell infiltration processing. [GRAPHICS] .