Journal of Crystal Growth, Vol.469, 31-35, 2017
Morphological evolution of copper nanoparticles: Microemulsion reactor system versus batch reactor system
In the synthesis of nanoparticles, the reaction rate is important to determine the morphology of nano particles. We investigated morphology evolution of Cu nanoparticles in this two different reactors, microemulsion reactor and batch reactor. In comparison with the batch reactor system, the enhanced mass and heat transfers in the emulsion system likely led to the relatively short nucleation time and the highly homogeneous environment in the reaction mixture, resulting in suppressing one or two dimensional growth of the nanoparticles. We believe that this work can offer a good model system to quantitatively understand the crystal growth mechanism that depends strongly on the local monomer concentration, the efficiency of heat transfer, and the relative contribution of the counter ions (Br- and Cl-) as capping agents. (C) 2016 Elsevier B.V. All rights reserved.