Journal of Crystal Growth, Vol.468, 175-178, 2017
Liquid-phase growth of few-layered graphene on sapphire substrates using SiC micropowder source
We demonstrated direct synthesis of graphene films consisting of a few layers (few-layered graphene) on sapphire substrates by liquid-phase growth (LPG), using liquid Ga as the melt and SiC micropowder as the source material. When the dissolution temperature was above 700 degrees C, almost all Si atoms of SiC diffused into the Ga melt and only carbon atoms remained at the interface beneath the liquid Ga. Above 800 degrees C, X-ray photoelectron spectra showed that most of the remaining carbon was graphitized. When the dissolution temperature was 1000 degrees C, Raman spectra showed that few-layered graphene films grew on the sapphire substrates.
Keywords:Characterization;Low dimensional structures;Nanostructure;Phase diagrams;Liquid phase epitaxy;Nanomaterials