화학공학소재연구정보센터
Journal of Physical Chemistry, Vol.100, No.49, 19182-19186, 1996
Stirring Effect on the Bistability of the Belousov-Zhabotinsky Reaction in a CSTR
Experiments show that the hysteresis of the bistable Belousov-Zhabotinsky reaction contracts along the directions of both the control parameter and the response variable as the stirring rate is decreased. A one-dimensional stochastic model reproduces qualitatively and quantitatively the effect of stirring on both steady states and hysteresis limits. The model suggests a classification of known stirring effects, A system behaves effectively one-dimensionally when its hysteresis contracts at low stirring. Otherwise, the system is described by at least two dynamical variables.