Interface structure between Li and garnet-type Li6.5La3Zr1.5Ta0.5O12 (LLZT) solid electrolyte was investigated by means of electrochemical impedance spectroscopy (EIS) on symmetric cells of Li vertical bar LLZT vertical bar Li. Charge transfer resistance (R-CT) between Li and LLZT was investigated using LLZT pellets with various roughness. R-CT and activation energy (E-a) obtained on the flat interface is as high as 746 Omega cm(2) and 0.51 eV at 25 degrees C, respectively, indicating that the charge transfer reaction at Li vertical bar LLZT (grit number: #8000) interface is a kinetically slow process, which may suppress rate capability of all solid-state batteries. Although the lowest R-CT of 363 Omega cm(2) was obtained by heating up to the melting point of Li for the LLZT pellet polished with an emery paper (#400), it is supposed that electrochemically effective contact area was saturated for rougher surfaces of LLZT. To prepare interfaces with large effective contact area, Li electrodes were deposited on a LLZT pellet by vacuum-evaporation, which exhibited further low R-CT of 69 Omega cm(2). The interface with large effective contact area is also a key to prevention of short circuit, and a high critical current density of 0.4 mA cm(-2) was demonstrated. (C) 2017 The Electrochemical Society. All rights reserved.