화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.164, No.4, F379-F386, 2017
Can We Quantify Oxygen Transport in the Nafion Film Covering an Agglomerate of Pt/C Particles?
We report a model of the cathode catalyst layer (CCL) impedance, which includes impedances due to oxygen transport in the Nafion film covering Pt/C agglomerates, and due to oxygen transport through the CCL depth. In the case of small cell current density, analytical solutions for the CCL impedance Z(ccl) are derived; for larger currents, we analyze numerical solution for Z(ccl). The characteristic frequencies of the oxygen transport through the Nafion film and through the CCL depth are close to each other, and the contribution of the Nafion film impedance Z(N) to Z(ccl) is small up to the current densities similar or equal to 100 mA cm(-2). This makes it difficult reliable determination of Z(N) from experimental spectra of a standard 10 mu m-thick CCL. However, with the decrease in the CCL thickness, the relative contribution of Z(N) to Z(ccl) increases. It gives us a chance to determine Z(N) by fitting the models of this work to measured spectra of a low-loaded MEA with a thin CCL. An example of fitting the model to a synthetic numerical impedance is given. (C) The Author(s) 2017. Published by ECS.