화학공학소재연구정보센터
Macromolecules, Vol.50, No.11, 4144-4150, 2017
Multifunctional Stimuli-Responsive Supramolecular Materials with Stretching, Coloring, and Self-Healing Properties Functionalized via Host-Guest Interactions
The visualization of changes in the stress and bonding state inside polymeric materials is an attractive function in materials science. In this study, phenolphthalein (PP) was selected to prepare stimuli-responsive coloring materials. PP becomes purple under basic conditions in aqueous solutions; however, PP becomes colorless under basic conditions when it forms a complex with beta-cydodextrin (beta CD). To exploit this property of PP, we prepared a color changing hydrogel (beta CD-PP AAm hydrogel) based on acrylamide (AAm) as the main chain and beta CD and PP moieties as the side chains. The beta CD-PP AAm hydrogel exhibits a color change when heat or a competing molecule is applied at a pH less than 8. This color change was confirmed by ultraviolet visible (UV-vis) spectroscopy, and the mechanical properties were determined via compression and tensile measurements. The beta CD-PP AAm hydrogel also exhibits a rapid, reversible color change upon Joule heating produced by an electric current passing through the gel.