PROGRESS IN MATERIALS SCIENCE, Vol.88, 325-411, 2017
Lithium garnets: Synthesis, structure, Li+ conductivity, Li+ dynamics and applications
Inorganic solid fast Li+ conductors based batteries are expected to overcome the limitations over safety concerns of flammable organic polymer electrolytes based Li+ batteries. Hence, an all-solid-state Li+ battery using non-flammable solid electrolyte have attracted much attention as next-generation battery. Therefore, in the development of all-solid-state lithium rechargeable batteries, it is important to search for a solid electrolyte material that has high Li+ conductivity, low electronic conductivity, fast charge transfer at the electrode interface and wide electrochemical window stability against potential electrodes and lithium metal. Hence, significant research effort must be directed towards developing novel fast Li+ conductors as electrolytes in all-solid-state lithium batteries. Among the reported inorganic solid Li+ conductive oxides, garnet-like structural compounds received considerable attention in recent times for potential application as electrolytes in all-solid-state lithium batteries. The focus of this review is to provide comprehensive overview towards the importance of solid fast lithium ion conductors, advantages of lithium garnets over other ceramic lithium ion conductors and understanding different strategies on synthesis of lithium garnets. Attempts have also been made to understand relationship between the structure, Li+ conduction and Li+ dynamics of lithium garnets. The status of lithium garnets as solid electrolyte in electrochemical devices like all-solid state lithium battery, lithium-air battery and sensor are also discussed. (C) 2017 Elsevier Ltd. All rights reserved.
Keywords:Electrochemical energy storage devices;Rechargeable lithium battery technology;Solid fast Li+ conductors;Garnet structured fast Li+ conductors