화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.101, No.25, 4555-4559, 1997
Rotational Analyses for Selected Bands of the 2(1)Sigma(+)(U)(-Chi(1)Sigma(+)(G) Transition of Cl-2
Rotational analyses are presented for selected bands of the 2(1) Sigma(u)(+) v’ = 1-3) <-- X-1 Sigma(g)(+) (v " = 0) transition of supersonically cooled Cl-2, recorded in fluorescence excitation near lambda less than or equal to 128 nm with a tunable, coherent, and monochromatic vacuum ultraviolet laser generated by four-wave difference mixing in Kr gas. Absolute J-numbering was established in part by spectral simulation. Although the band system is perturbed, the effective rotational constants derived in this work are consistent with theoretical calculations that place the excited two-state equilibrium bond length at similar to 2.1 Angstrom.