Films of transparent conducting antimony-doped tin oxide have been deposited by sol-gel based Dip-coating technique. The morphological analysis revealed that the deposited films are homogenous, smooth and the roughness depends on the Sb-doping. The Raman scattering showed that the vibrational modes are sensitive to oxygen deficiency, structural disorder and were red-shifted compared to the rutile SnO2 single crystal. The FTIR study depicted the presence of Sn-O (610 cm(-1)) and Sn-O-Sn ( 740 cm(-1)) bonds in the films. Optical measurements revealed high transparency (similar to 85%) over the visible region. The optical band gap varies from 3.87 to 3.79 eV with increasing the width of tail states and corresponds to direct allowed transition in the bulk. The AC-conductivity (sigma(ac)) exhibits a semiconductor temperature-dependence behavior and varies from extrinsic to intrinsic conduction. The thermal energy promotes the polarization involving electrons localized at randomly oriented oxygen vacancies of the inhomogeneous dielectric structure grain/grain boundary and induces high dielectric constant. sigma(ac) was found to follow the power law: sigma(ac) = A. f(0.49) at high frequencies and the experimental results showed that the correlated barrier hopping mechanismis appropriate for the charge transfer between localized states. (C) 2017 Published by Elsevier B.V.