Electrochemical catalytic contribution of transition metals at the center of porphyrin macrocycle structures as catalysts for oxygen reduction reaction

Do-Hyoung Kim; Da-Hee Kwak; Sang-Beom Han; Min-Cheol Kim; Hyun-Suk Park; Jin-Young Park; Ji-Eun Won; Kyoung-Bae Ma; Kyung-Won Park

Journal of Industrial and Engineering Chemistry, Vol.54, 200-204, October, 2017

DOI10.1016/j.jiec.2017.05.034 Export Citation

Electrochemical catalytic contribution of transition metals at the center of porphyrin macrocycle structures as catalysts for oxygen reduction reaction

Do-Hyoung Kim, Da-Hee Kwak, Sang-Beom Han, Min-Cheol Kim, Hyun-Suk Park, Jin-Young Park, Ji-Eun Won, Kyoung-Bae Ma, and Kyung-Won Park^†

Department of Chemical Engineering, Soongsil University, Seoul 156-743, Republic of Korea

E-mail:

In a macrocyclic structure, the contribution of the metal-N4 sites to oxygen reduction reaction (ORR) remains controversial.In this study, to investigate the contribution of macrocyclic cathode catalysts to the ORR properties in the macrocyclic sites excluding various synthetic conditions, the macrocyclic cathode catalysts were prepared using an electrochemical polymerization method at room temperature. The ORR activity of the deposited electrodes as catalysts was evaluated in an alkaline medium. To clarify the core metal as an active site in the macrocyclic structure as a cathode catalyst for the ORR, a CN- -poisoning test of core metal site was performed.

Keywords:Porphyrin macrocycle structure;Non-precious catalyst;Electrochemical polymerization;Oxygen reduction reaction

[References]

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Liang W, Chen J, Liu Y, Chen S, ACS Catal., 4, 4170 (2014)
Dombrovskis JK, Jeong HY, Fossum K, Terasaki O, Palmqvist AEC, Chem. Mater., 25, 856 (2013)
Kojima I, Miyazaki E, Inoue Y, Yasumori I, J. Catal., 73, 128 (1982)
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Tang Y, Burkert SC, Zhao Y, Saidi WA, Star A, J. Phys. Chem., 48, 25213 (2013)
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Masa J, Xia W, Muhler M, Masa WSJ, Angew. Chem.-Int. Edit., 54, 10102 (2015)
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Yao B, Li C, Ma J, Shi G, Phys. Chem. Chem. Phys., 17, 19538 (2015)
Cheon JY, Kim TY, Choi YM, Jeong HY, Kim MG, Sa YJ, Kim JS, Lee ZH, Yang TH, Kwon KG, Terasaki O, Park GG, Adzic RR, Joo SH, Sci. Rep., 3, 2715 (2013)
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Pels JR, Carbon, 33, 1641 (1995)
Ramaswamy N, Tylus U, Jia QY, Mukerjee S, J. Am. Chem. Soc., 135(41), 15443 (2013)
Paul-Roth C, Rault-Berthelot J, Simonneaux G, Tetrahedron, 60, 12169 (2004)
Kearns JT, Roberts ME, J. Mater. Chem., 22, 25447 (2012)
He Q, Mugadza T, Hwang G, Nyokong T, Int. J. Electrochem. Sci., 7, 7045 (2012)
Paul-Roth C, Rault-Berthelot J, Simonneaux G, Poriel C, Abdalilah M, Letessier J, J. Electroanal. Chem., 597(1), 19 (2006)
Maruyama S, Segawa H, Sotoda S, Sato T, Kosai N, Sagisaka S, Shimidzu T, Tanaka K, Synth. Met., 96, 141 (1998)
Hassena LBH, Ezzayani K, Rousselin Y, Stern C, Nasri H, Schulz CE, J. Mol. Struct., 1110, 138 (2016)
Bazzaoui EA, Aeiyach S, Lacaze PC, J. Electroanal. Chem., 364(1-2), 63 (1994)
Mu XH, Kadish KM, Inorg. Chem., 27, 4120 (1998)
Thorum MS, Hankett JM, Gewirth AA, J. Phys. Chem., 2, 295 (2011)
Chen W, Akhigbe J, Bruckner C, Li CM, Lei Y, J. Phys. Chem., 114, 8633 (2010)
Adler AD, Longo FR, Shergalis W, J. Am. Chem. Soc., 86, 3145 (1964)
Palma-Cando A, Brunklaus G, Scherf U, Macromolecules, 48(19), 6816 (2015)
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[Referenced By]

[1] Lai L, Potts JR, Zhan D, Wang L, Poh CK, Tang C, Gong H, Shen Z, Lin J, Ruoff RS, Energy Environ. Sci., 5, 7936 (2012)

[2] Maruyama J, Fukui N, Kawaguchi M, Abe I, J. Power Sources, 182(2), 489 (2008)

[3] Lefevre M, Proietti E, Jaouen F, Dodelet J, Lefevre M, Science, 324, 71 (2009)

[4] Bezerra CWB, Zhang L, Lee KC, Liu HS, Marques ALB, Marques EP, Wang HJ, Zhang JJ, Electrochim. Acta, 53(15), 4937 (2008)

[5] Daems N, Sheng X, Vankelecom IFJ, Pescarmona PP, J. Mater. Chem., 2, 4085 (2014)

[6] Pan F, Jin J, Fu X, Liu Q, Zhang J, ACS Appl. Mater. Interfaces, 21, 11108 (2013)

[7] Liang W, Chen J, Liu Y, Chen S, ACS Catal., 4, 4170 (2014)

[8] Dombrovskis JK, Jeong HY, Fossum K, Terasaki O, Palmqvist AEC, Chem. Mater., 25, 856 (2013)

[9] Kojima I, Miyazaki E, Inoue Y, Yasumori I, J. Catal., 73, 128 (1982)

[10] He Q, Mugadza T, Hwang G, Nyokong T, Int. J. Electrochem. Sci., 7, 7045 (2012)

[11] Tang Y, Burkert SC, Zhao Y, Saidi WA, Star A, J. Phys. Chem., 48, 25213 (2013)

[12] Jasinski R, Nature, 201, 1212 (1964)

[13] Masa J, Xia W, Muhler M, Masa WSJ, Angew. Chem.-Int. Edit., 54, 10102 (2015)

[14] Wu G, More KL, Johnston CM, Zelenay P, Science, 332(6028), 443 (2011)

[15] Du J, Cheng F, Wang S, Zhang T, J. Chen, Sci. Rep., 4, 4386 (2014)

[16] Yao B, Li C, Mab J, Shi G, Chen J, Liu J, Jurcakova DH, Jaroniec M, Qiao SZ, Angew. Chem.-Int. Edit., 51, 3892 (2012)

[17] Yao B, Li C, Ma J, Shi G, Phys. Chem. Chem. Phys., 17, 19538 (2015)

[18] Cheon JY, Kim TY, Choi YM, Jeong HY, Kim MG, Sa YJ, Kim JS, Lee ZH, Yang TH, Kwon KG, Terasaki O, Park GG, Adzic RR, Joo SH, Sci. Rep., 3, 2715 (2013)

[19] Schulenburg H, Stankov S, Schunemann V, Radnik J, Dorbandt I, Fiechter S, Bogdanoff P, Tributsch H, J. Phys. Chem. B, 107(34), 9034 (2003)

[20] Pels JR, Carbon, 33, 1641 (1995)

[21] Ramaswamy N, Tylus U, Jia QY, Mukerjee S, J. Am. Chem. Soc., 135(41), 15443 (2013)

[22] Paul-Roth C, Rault-Berthelot J, Simonneaux G, Tetrahedron, 60, 12169 (2004)

[23] Kearns JT, Roberts ME, J. Mater. Chem., 22, 25447 (2012)

[24] He Q, Mugadza T, Hwang G, Nyokong T, Int. J. Electrochem. Sci., 7, 7045 (2012)

[25] Paul-Roth C, Rault-Berthelot J, Simonneaux G, Poriel C, Abdalilah M, Letessier J, J. Electroanal. Chem., 597(1), 19 (2006)

[26] Maruyama S, Segawa H, Sotoda S, Sato T, Kosai N, Sagisaka S, Shimidzu T, Tanaka K, Synth. Met., 96, 141 (1998)

[27] Hassena LBH, Ezzayani K, Rousselin Y, Stern C, Nasri H, Schulz CE, J. Mol. Struct., 1110, 138 (2016)

[28] Bazzaoui EA, Aeiyach S, Lacaze PC, J. Electroanal. Chem., 364(1-2), 63 (1994)

[29] Mu XH, Kadish KM, Inorg. Chem., 27, 4120 (1998)

[30] Thorum MS, Hankett JM, Gewirth AA, J. Phys. Chem., 2, 295 (2011)

[31] Chen W, Akhigbe J, Bruckner C, Li CM, Lei Y, J. Phys. Chem., 114, 8633 (2010)

[32] Adler AD, Longo FR, Shergalis W, J. Am. Chem. Soc., 86, 3145 (1964)

[33] Palma-Cando A, Brunklaus G, Scherf U, Macromolecules, 48(19), 6816 (2015)

[34] Birry L, Zagal JH, Dodelet JP, Electrochem. Commun., 12, 628 (2010)

[35] Yin W, Chen C, Fa H, Zhang L, J. Solid State Electrochem., 17, 3095 (2013)