화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.54, 278-289, October, 2017
DOI10.1016/j.jiec.2017.06.002  Export Citation
Separation of platinum(IV) across hollow fiber supported liquid membrane using non-toxic diluents: Mass transfer and thermodynamics
Krirkratthawit Wongkaew, Vanee Mohdee, Ura Pancharoen†, Amornchai Arpornwichanop†, and Anchaleeporn W. Lothongkum1
  • Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Pathumwan, Bangkok 10330, Thailand
  • 1Department of Chemical Engineering, Faculty of Engineering, King Mongkut’s Institute of Technology Ladkrabang, Bangkok 10520, Thailand
E-mail:,
Non-toxic diluents were studied and compared with toxic diluents for separation of platinum(IV) across hollow fiber supported liquid membrane. 91.41% extraction and 81% stripping of platinum(IV) was observed for sunflower oils at 328.15 K. Overall mass transfer resistance (R) was 146.612 x10 4 s/cm. The separation process was exothermic (ΔH0 ex = -975.20 kJ/mol) and spontaneous (ΔG 0 ex = -326.447 J/mol). The Ea of 1.673 kJ/mol indicated that the diffusion of complex species across the liquid membrane controlled the mass transfer step. Moreover, a modified Apelblat model gave an excellent match for predicting the extraction behavior of platinum(IV) at 1.2818% RMSD.
Keywords:Platinum(IV);Non-toxic diluents;Sunflower oils;Thermodynamics;HFSLM
  1. Gupta B, Singh I, Hydrometallurgy, 134, 11 (2013)
  2. Wongkaew K, Wannachod T, Mohdee V, Pancharoen U, Arpornwichanop A, Lothongkum AW, J. Ind. Eng. Chem., 42, 23 (2016)
  3. Zhang WD, Cui CH, Ren ZQ, Dai Y, Meng HL, Chem. Eng. J., 157(1), 230 (2010)
  4. Pei L, Wang LM, Guo W, Zhao N, Acta Chim. Sin., 69, 1553 (2011)
  5. Zheng HD, Chen JJ, Wang BY, Zhao SY, Chin. J. Chem. Eng., 21(8), 827 (2013)
  6. Vilt ME, Ho WSW, J. Membr. Sci., 367(1-2), 71 (2011)
  7. Vernekar PV, Patwardhan AW, Patwardhan AV, Ansari SA, Mohapatra PK, Manchanda VK, Sep. Sci. Technol., 48(7), 1003 (2013)
  8. Adya VC, Sengupta A, Ansari S, Mohapatra PK, Bhide MK, Godbole SV, J. Radioanal. Nucl. Chem., 295, 1023 (2013)
  9. Chang SH, Teng TT, Ismail N, J. Hazard. Mater., 181(1-3), 868 (2010)
  10. Chakrabarty K, Saha P, Ghoshal AK, J. Membr. Sci., 350(1-2), 395 (2010)
  11. Kazemi P, Peydayesh M, Bandegi A, Mohammadi T, Bakhtiari O, Chem. Pap., 67, 722 (2013)
  12. Venkateswaran P, Gopalakrishnan AN, Palanivelu K, J. Environ. Sci. China, 19, 1446 (2007)
  13. Chaturabul S, Srirachat W, Wannachod T, Ramakul P, Pancharoen U, Kheawhom S, Chem. Eng. J., 265, 34 (2015)
  14. Lothongkum AW, Ramakul P, Sasomsub W, Laoharochanapan S, Pancharoen U, J. Taiwan Inst. Chem. Eng., 40, 518 (2009)
  15. Lothongkum AW, Suren S, Chaturabul S, Thamphiphit N, Pancharoen U, J. Membr. Sci., 369(1-2), 350 (2011)
  16. Suren S, Wongsawa T, Pancharoen U, Prapasawat T, Lothongkum AW, Chem. Eng. J., 191, 503 (2012)
  17. Sunsandee N, Leepipatpiboon N, Ramakul P, Wongsawa T, Pancharoen U, Sep. Purif. Technol., 102, 50 (2013)
  18. Nguyen VT, Lee JC, Chagnes A, Kim MS, Jeong J, Cote G, RSC Adv., 6, 62717 (2016)
  19. Fontas C, Salvado V, Hidalgo M, Solvent Extr. Ion Exch., 17, 149 (1999)
  20. Lee JY, Kumar JR, Kim JS, Kim DJ, Yoon HS, J. Ind. Eng. Chem., 15(3), 359 (2009)
  21. Alpoguz HK, Kaya A, Sener I, J. Macromol. Sci. A, 44, 1061 (2007)
  22. Arisaka M, Kimura T, Solvent Extr. Ion Exch., 29, 72 (2011)
  23. Adhikari BB, Gurung M, Kawakita H, Ohto K, Solvent Extr. Ion Exch., 31, 483 (2013)
  24. Davarkhah R, Khanramaki F, Asgari M, Salimi B, Ashtari P, Shamsipur M, J. Radioanal. Nucl. Chem. 1 (2013).
  25. Tang YX, Liu W, Wan JL, Wang YX, Yang XL, Process Biochem., 48(12), 1980 (2013)
  26. Ren ZQ, Meng HL, Zhang WD, Liu JT, Cui CH, Sep. Sci. Technol., 44(5), 1181 (2009)
  27. Wickramasinghe SR, Semmens MJ, Cussler EL, J. Membr. Sci., 69, 235 (1992)
  28. Baudot A, Floury J, Smorenburg HE, AIChE J., 47(8), 1780 (2001)
  29. Vernekar PV, Jagdale YD, Patwardhan AW, Patwardhan AV, Ansari SA, Mohapatra PK, Manchanda VK, Chem. Eng. Res. Des., 91(1), 141 (2013)
  30. Liu X, Hu YH, Yang WG, Liu Y, Liang MM, Fluid Phase Equilib., 360, 134 (2013)
  31. Yu GM, Wang LS, Jiang LK, Sun J, Fluid Phase Equilib., 396, 50 (2015)
  32. Wu C, Li J, Dong H, Jiang JX, Thermochim. Acta, 543, 24 (2012)
  33. Esteban B, Riba JR, Baquero G, Puig R, Rius A, Fuel, 102, 231 (2012)
  34. Tangsathitkulchai C, Sittichaitaweekul Y, Tangsathitkulchai M, J. Am. Oil Chem. Soc., 81, 401 (2004)
  35. Parente RC, Nogueira CA, Carmo FR, Lima LP, Fernandes FAN, Santiago-Aguiar RS, Sant'Ana HB, J. Chem. Eng. Data, 56(7), 3061 (2011)
  36. Sanaiotti G, da Silva CAS, Parreira AG, Totola MR, Meirelles AJA, Batista EAC, J. Chem. Eng. Data, 55(11), 5237 (2010)
  37. Melo-Espinosa EA, Sanchez-Borroto Y, Errasti M, Piloto-Rodriguez R, Sierens R, Roger-Riba J, Christopher-Hansen A, Energy Procedia, 57, 886 (2014)
  38. Allen CAW, Watts KC, Ackman RG, J. Am. Oil Chem. Soc., 76, 317 (1999)
  39. Wongsawa T, Leepipatpiboon N, Thamphiphit N, Pancharoen U, Lothongkum AW, Chem. Eng. J., 222, 361 (2013)
  40. Mafu LD, Msagati TAM, Mamba BB, Phys. Chem. Earth, 50-52, 121 (2012)
  41. Chaturabul S, Wongkaew K, Pancharoen U, Sep. Sci. Technol., 48(1), 93 (2013)
  42. Nguyen VT, Lee JC, Chagnes A, Kim MS, Jeong J, Cote G, RSC Adv., 6, 62717 (2016)
  43. Sharma AD, Patwardhan AW, Ansari SA, Mohapatra PK, Sep. Sci. Technol., 50(3), 332 (2015)
  44. Mao YL, Chen H, Han J, Wang Y, Tang X, Ni L, Wang L, J. Iran. Chem. Soc., 13, 403 (2016)
  45. Wongkaew K, Sunsandee N, Pancharoen U, Nootong K, Ramakul P, J. Ind. Eng. Chem., 22, 217 (2015)
  46. Wongkaew K, Pancharoen U, Phatanasri S, Leepipatpiboon N, Lothongkum AW, J. Ind. Eng. Chem., 21, 212 (2015)
  47. Wannachod T, Leepipatpiboon N, Pancharoen U, Nootong K, Chem. Eng. J., 248, 158 (2014)
  48. Wongkaew K, Wannachod T, Mohdee V, Pancharoen U, Arpornwichanop A, Lothongkum AW, J. Ind. Eng. Chem., 42, 23 (2016)
  49. Alguacil FJ, Caravaca C, Martin MI, J. Chem. Technol. Biotechnol., 78(10), 1048 (2003)
  50. Sunsandee N, Ramakul P, Pancharoen U, Leepipatpiboon N, Sep. Purif. Technol., 116, 405 (2013)
  51. Lee JY, Kumar JR, Kim JS, Park HK, Yoon HS, J. Hazard. Mater., 168(1), 424 (2009)
  52. Yang XJ, Fane AG, Pin C, Chem. Eng. J., 88(1-3), 37 (2002)
  53. Buachuang D, Ramakul P, Leepipatpiboon N, Pancharoen U, J. Alloy. Compd., 509, 9549 (2011)
  54. Hajarabeevi N, Bilal IM, Easwaramoorthy D, Palanivelu K, Desalination, 245(1-3), 19 (2009)
  55. Fasina OO, Colley Z, Int. J. Food Prop., 11, 738 (2008)
  56. Michel M, Chimuka L, Cukrowska E, Wieczorek P, Buszewski B, Anal. Chim. Acta, 632, 86 (2009)
  57. El-Nadi YA, El-Hefny NE, Aly HF, Int. J. Min. Metall. Mater., 20, 713 (2013)
  58. Kong F, Liao JL, Ding SD, Yang YY, Huang H, Yang JJ, Tang J, Liu N, J. Radioanal. Nucl. Chem., 298, 651 (2013)
  59. Clement C, Hossain MM, Sep. Sci. Technol., 32(16), 2685 (1997)
  60. Ong YT, Yee KF, Cheng YK, Tan SH, Sep. Purif. Rev., 43, 62 (2014)
  61. Szpakowska M, Nagy OB, J. Membr. Sci., 129(2), 251 (1997)
  62. Kocherginsky NM, Yang Q, Seelam L, Sep. Purif. Technol., 53(2), 171 (2007)
  63. Guell R, Antico E, Salvado V, Fontas C, Sep. Purif. Technol., 62(2), 389 (2008)
  64. Fontas C, Palet C, Salvado V, Hidalgo M, J. Membr. Sci., 178(1-2), 131 (2000)