염화철 에칭폐액의 용매추출공정 최적화에 관한 연구

박일정; 김대원; 김건홍; 채홍준; 이상우; 정항철; Il-Jeong Park; Dae-Weon Kim; Geon-Hong Kim; Hong-jun Chae; Sang-Woo Lee; Hang-Chul Jung

Clean Technology, Vol.23, No.3, 279-285, September, 2017

DOI10.7464/ksct.2017.23.3.279 Export Citation

염화철 에칭폐액의 용매추출공정 최적화에 관한 연구

The Optimization of Solvent Extraction Process of Iron Chloride Etching Waste Solution

박일정^†, 김대원, 김건홍, 채홍준, 이상우¹, 정항철

고등기술연구원 신소재공정센터, 17180 경기 용인시 처인구 백암면 고안로 51번길 175-28
¹(주)케이엠씨, 39414 경북 구미시 3공단3로 40

Il-Jeong Park^†, Dae-Weon Kim, Geon-Hong Kim, Hong-jun Chae, Sang-Woo Lee¹, and Hang-Chul Jung

Advanced Materials and Processing Center, Institute for Advanced Engineering (IAE), 175-28, Goan-ro 51beon-gil, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi, 17180, Korea
¹KMC Co., Ltd., 40, 3gongdan 3-ro, Gumi-si, Gyeongbuk, 39414, Korea

E-mail:

초록

본 연구에서는 염화철 에칭폐액 재생을 위하여 ㈜케이엠씨에서 조합한 organophosphorus acid계의 신규용매(KMC-P)를 사용하였으며, 용매추출공정에서 신규 용매에 대한 추출효율을 증가시키기 위해 공정변수를 선정하고 변수간의 상관관계를 알아보기 위해서 DOE에 따른 최적화실험을 진행하였다. 용매 농도, pH, O/A ratio가 추출, 탈거효율에 영향을 미치는 인자로 나타났으며 최적의 탈거효율을 갖는 공정조건은 용매 농도 29.4 wt%, HCl 첨가량 0 mL, O/A ratio 7일 때, 최대 69.7%의 탈거효율을 기대할 수 있는 결과를 얻었으며 신뢰 수준은 86% 이상인 것을 확인하였다.

In this study, a new organophosphorus acid-based solvent (KMC-P) from KMC Co., Ltd. was used for the recovery of the iron chloride etching waste solution. In order to increase the extraction efficiency for the new solvent in the solvent extraction process, we selected the process variables and conducted the optimization experiment according to the DOE to investigate the correlation between the variables. Solvent concentration, pH, and O/A ratio were found to be factors affecting extraction and stripping efficiency. The optimum stripping efficiency was 69.7% when the solvent concentration was 29.4 wt%, the HCl addition amount was 0 mL, and the O/A ratio was 7, and the reliability was more than 86%.

Keywords:Nickel recovery;Solvent extraction;Extraction efficiency;Stripping efficiency;Optimization

[References]

Lewis RJ, Sax's Dangerous Properties of Industrial Materials, 8th ed., Van Norstrand Reinhold, New York (1992).
Sayar NA, Sayar AA, Filiz M, Hydrometallurgy, 95, 280 (2009)
Reddy BR, Priya DN, Anal. Sci. Technol., 20, 1737 (2004)
Singh R, Khwaja AR, Gupta B, Tandon SN, Solvent Extr. Ion Exch., 17(2), 367 (1999)
Park KH, Mohapatra D, Met. Mater. Int., 12(5), 441 (2006)
Preston JS, Hydrometallurgy, 9, 115 (1982)
Pashkov GL, Grigorieva NA, Pavlenko NI, Fleitlikh IY, Nikiforova LK, Pleshkov MA, Solvent Extr. Ion Exch., 26(6), 749 (2008)
Koladkar DV, Dhadke PM, Solvent Extr. Ion Exch., 19(6), 1059 (2001)
Komasawa I, Otake T, Hattori I, J. Chem. Engg. Jpn., 16, 384 (1983)
Huang TC, Tsai TH, Ind. Eng. Chem. Res., 28, 1557 (1989)
Nan J, Han D, Yang M, Cui M, Hou X, Hydrometallurgy, 84, 75 (2006)
Ahn JG, Ahn JW, Lee MS, J. Korean Inst. Met. & Mater., 40(7), 799 (2002)
Cerpa A, Alguacil FJ, J. Chem. Technol. Biotechnol., 79, 455 (2002)
Sarangi K, Reddy BR, Das RP, Hydrometallurgy, 52, 253 (1999)
Sole KC, Hiskey JB, Hydrometallurgy, 30, 345 (1992)

[Referenced By]

[1] Lewis RJ, Sax's Dangerous Properties of Industrial Materials, 8th ed., Van Norstrand Reinhold, New York (1992).

[2] Sayar NA, Sayar AA, Filiz M, Hydrometallurgy, 95, 280 (2009)

[3] Reddy BR, Priya DN, Anal. Sci. Technol., 20, 1737 (2004)

[4] Singh R, Khwaja AR, Gupta B, Tandon SN, Solvent Extr. Ion Exch., 17(2), 367 (1999)

[5] Park KH, Mohapatra D, Met. Mater. Int., 12(5), 441 (2006)

[6] Preston JS, Hydrometallurgy, 9, 115 (1982)

[7] Pashkov GL, Grigorieva NA, Pavlenko NI, Fleitlikh IY, Nikiforova LK, Pleshkov MA, Solvent Extr. Ion Exch., 26(6), 749 (2008)

[8] Koladkar DV, Dhadke PM, Solvent Extr. Ion Exch., 19(6), 1059 (2001)

[9] Komasawa I, Otake T, Hattori I, J. Chem. Engg. Jpn., 16, 384 (1983)

[10] Huang TC, Tsai TH, Ind. Eng. Chem. Res., 28, 1557 (1989)

[11] Nan J, Han D, Yang M, Cui M, Hou X, Hydrometallurgy, 84, 75 (2006)

[12] Ahn JG, Ahn JW, Lee MS, J. Korean Inst. Met. & Mater., 40(7), 799 (2002)

[13] Cerpa A, Alguacil FJ, J. Chem. Technol. Biotechnol., 79, 455 (2002)

[14] Sarangi K, Reddy BR, Das RP, Hydrometallurgy, 52, 253 (1999)

[15] Sole KC, Hiskey JB, Hydrometallurgy, 30, 345 (1992)