Applied Catalysis A: General, Vol.546, 122-125, 2017
Manganese incorporated on glucose as an efficient catalyst for the synthesis of adipic acid using molecular O-2 in aqueous medium
A new manganese incorporated on glucose catalyst Mn@CC-SO3H-NH2 was synthesized and well characterized using FT-IR, PXRD, EDAX, SEM, TEM, [13] C cross-polarization NMR and BET analysis. The catalyst thus synthesized was studied for its utility in the synthesis of industrially important chemical adipic acid starting from readily available cyclohexanone using molecular O-2 as a source. Adipic acid was obtained in maximum yield of 82% using Mn@CC-SO3H-NH2 catalyst in water as a solvent. The catalyst was easily recovered and reused for minimum five runs without any significant loss in the yield of products. Using molecular O-2 as an oxidant and water as a solvent, the reaction is very important from green chemistry perspectives and can also be industrially feasible.