화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.102, No.11, 1903-1905, 1998
Sudden approximation mass validity criteria values for accurate transition probabilities in two-mode collinear collisions
By comparing approximate and exact transition probabilities for several new collision systems, we have established lower, less restrictive, values for validity criteria for use in predicting which collinear atom-triatom or diatom-diatom collision systems could be reliably treated in the vibrational sudden approximation. The specific lower bounds for the atom-triatom (A + 1-2-1) validity criterion, 2m(1)(2m(1) + m(2) +m(A))/[m(A)(2m(1) + m(2))], and the diatom-diatom (A(2) + B-2) validity criterion, m(B)/3m(A), are 14 and 6, respectively.