Chemical Physics Letters, Vol.684, 219-224, 2017
The effect of flow rate on the oscillatory activation energy of an oscillating reaction
The simultaneous influence of temperature and flow rate (k(0)) in the oscillatory regime of the bromate-oxalic acid-acetone-Ce(III) oscillating reaction was investigated. The influence of temperature was evaluated in terms of the oscillatory activation energy (E-omega), which was determined at different flow rates. Increasing k(0), the oscillatory activation energy is decreased, tending to a limit value, E-omega infinity. The sensitivity of E-omega, with k(0) is described by the parameter eta = dE omega/d(1/k(0)). E-omega infinity and eta are global properties of any particular oscillating reaction and describes a correlation between the dynamical behavior and temperature, and should be used when comparing different oscillating reactions. (C) 2017 Elsevier B.V. All rights reserved.