Energy Conversion and Management, Vol.148, 330-338, 2017
Experimental investigation on a novel solid-gas thermochemical sorption heat transformer for energy upgrade with a large temperature lift
Heat transformer is an effective technology for the recovery and reutilization of low-grade waste heat by upgrading its temperature to meet the energy demand. Low temperature-lift capacity is the common drawback for conventional heat transformers based on sorption process or heat pumps. A novel solid gas thermochemical` sorption heat transformer was developed for the energy upgrade of low-grade waste heat with a large temperature lift based on the pressure-reducing desorption and temperature-lifting adsorption techniques. The working performance and feasibility of the large-temperature-lift thermochemical sorption heat transformer was investigated and analyzed using a group of sorption working pairs of MnCl2-SrCl2-NH3. Expanded graphite was employed as the porous additive to enhance the heat and mass transfer of reactive salts. The experimental results showed that the proposed solid-gas thermochemical sorption heat transformer is feasible to achieve energy upgrade with a large temperature lift. It has the potential to upgrade the low-grade heat from 96 degrees C to 161 degrees C using MnCl2-SrCl2-NH3 sorption working pairs, and the exergy efficiency and energy efficiency are as high as 0.75 and 0.43, respectively. The temperature-lift range is relevant to the global conversion of reactive salt and sensible heat consumption, of reactor. It is desirable to improve the temperature-lift range and energy efficiency by increasing the global conversion and decreasing the mass ratio of metallic part of reactor to reactive salt. (C) 2017 Elsevier Ltd. All rights reserved.
Keywords:Energy upgrade;Thermochemical sorption;Heat transformer;Energy efficiency;Exergy efficiency