Neat (100%) n-butanol was implemented in a direct injection (DI) compression ignition (CI) engine. The ignition, combustion, and emission characteristics at low engine load (below 6.5 bar IMEP), including near idling, were investigated. The engine experiments were performed using a modern common rail type single cylinder DI CI engine with a compression ratio of 18.2: 1. Chemical kinetic simulations were also conducted to analyze the ignition characteristics of the experiments. The research results showed that neat n-butanol could not be auto-ignited at normal intake temperature and pressure conditions due to its low reactivity. However, the use of a high intake pressure of 0.75 bar gauge, and an injection timing of -26 degrees ATDC at 5.0 bar IMEP, enabled auto-ignition even without the use of intake heating. One possible reason for this was attributed to the enhancement of the low temperature reaction regime. The ignition timing advancement sensitivity to intake pressure was approximately 1.0 degrees CA/0.1 bar at 5.0 bar IMEP, and a higher intake pressure allowed a wider injection timing range. A neat n-butanol fueled DI CI engine had a five times longer ignition delay and a 85% longer combustion duration than the same engine fueled with diesel at 2.0 bar IMEP. However, the combustion duration tended to shorten rapidly with increasing engine load, which was the opposite tendency to diesel. At low load, the nitrogen oxides (NOx) and soot emissions were very low compared to those of diesel, whereas the total hydrocarbons (THC), formaldehyde (HCHO), and carbon monoxide (CO) were higher than those of diesel. Carbon dioxide (CO2) emission was lower than that of diesel. This could be due to the reduced CO oxidation and the lower carbon content in n-butanol. Finally, by combining the previously published results with these results in this research, fuel injection strategies and intake oxygen conditions required to achieve low NOx (<= 0.60 g/kWh) and soot (<= 0.02 g/kWh) emissions and moderated maximum cylinder pressure rise rate (<= 10 bar/degrees CA) were summarized over a wide load range of 2.0-11.5 bar IMEP. (C) 2017 Elsevier Ltd. All rights reserved.