화학공학소재연구정보센터
Fuel Processing Technology, Vol.167, 582-607, 2017
Process simulation of a fluidized-bed catalytic cracking process for the conversion of algae oil to biokerosene
The ambitious targets of the aviation industry to reduce greenhouse gas emissions require the use of biofuels in this transport sector in the short and medium term. While five biogenic aviation turbine fuels have already been certified by the American Society for Testing and Materials (ASTM D7566), the search for suitable alternatives continues, seeking higher possible blending ratios or better fuel qualities. Fluidized-bed catalytic cracking (FCC) of algae oil, followed by hydrotreatment of intermediates, could be such a potential option. This conversion concept has several potential advantages, such as aromatic compounds in the biokerosene and the use of a non-food biogenic oil as feedstock. Material and energy balances are obtained from flowsheet simulation using ASPEN Plus (R), with the aim to assess the efficiency of the process. The simulation model contains all relevant conversion and separation steps, and auxiliary components such as a steam reformer and a furnace. Simulation parameters for all unit operations were based on current literature to represent the state-of-the-art of the involved technologies. Additionally, the process was optimized by heat integration and waste heat utilization. The established simulation model is proposed to serve as a concept study and basis for the implementation of future experimental results and perceptions. With an energy efficiency of 95% and a biokerosene yield of 41%, the results emphasize the potential of this conversion process.