Various biocrudes were characterised by their distillation curves using simulated distillation. Biocrude and petroleum crude blends were generated and analysed to assess their compatibility for processing in conventional petroleum refineries. Distillation curves of biocrudes varied widely but were comparable to petroleum crude oil in shape and distillation range. Blending biocrude with petroleum crudes in the laboratory presented some challenges in miscibility; however, blending at higher than ambient temperatures, which more closely represents industrial practice, improved miscibility as shown in the FTIR spectra of blends, and close matching of the warmer blends to models. The distillation curve of the biocrude-petroleum crude blends followed the modelled blends in ASPEN Plus. Petroleum analysis and modelling methods were also demonstrated as reliable tools to analyse biocrudes and their blends with petroleum crude. The study verifies ASPEN's utility in modelling biocrude distillation for processing in refinery distillation columns either as a blend or separately.