We report that reactions of the binary organotin sulfide cluster [((RSn)-Sn-1)(3)S-4]Cl [A; R-1 = CMe2CH2C(O)Me] with gold(I) phosphane complexes yield discrete ternary complexes [((RSn)-Sn-1)(2)(AuPMe3)(2)S-4] (1) and [((RSn)-Sn-2)(2)(AuPMe3)(2)S-4] [2; R-2 = CMe2CH2C(NNH2)Me], which are related to recently published complexes [((RSn)-Sn-1,2)(2)(AuPPh3)(2)S-4] (B and C). Further, we present a binary tin sulfide cluster that cocrystallizes with a structure directing salt of a gold phosphane complex in [Au(dppe)(2)]-[((RSn)-Sn-3)(4)S6Cl] [3; R-3 = CMe2CH2C(NNHPh)Me]. The nature of the product depends on the choice of the phosphane ligand as well as the addition of hydrazine hydrate or phenylhydrazine. Additionally, we report on the photophysical properties of 1, 2, B, and C, which indicate that the different phosphane ligands only have a slight influence on the optical responses. The structure, however, has a significant impact on the luminescence efficiency.