The recent upsurge in research on coordination polymer gels (CPGs) steins from their synthetic modularity, nanoscale processability, and versatile functionalities. Here we report self-assembly of an amphiphilic, tripodal low-molecular weight gelator (L) that consists of 4,4',4-[1,3,5-phenyl-tri(methoxy)]-tris-benzene core and 2,2':6',2"-terpyridyl termini, with different metal ions toward the formation of CPGs that show controllable nanomorphologies, tunable emission, and stimuli tesponsive behaviors. L can also act as a selective chemosensor for Zn-II with very low limit of daection (0.18 ppm) in aqueous medium. Coordination-driven self-assembly of L with Zn-II H2O/MeOH solvent mixture results in a coordination polymer hydrogel (ZOL), that exhibits sheet like morphology and charge-transfer emission. On the other hand, coordination of L with Tb-III and Eu-III in CHCl3/tetrahydrofuran solvent mixture resiflts: in green, and red-emissive CPGs, respectively, with nanotubular morphology. Moreover; precise stoichiometric control of L/Eu-III/Tb-III ratio leads to the formation of bimetallic CPGs that show emissions over a broad spectral range, including white-light-emission, We also explore the multistimuli responsive properties of the white-light-emitting CPG by exploiting the dynamics of Ln(III)-tpy coordination.