Organic inorganic hybrid lead halide (e.g., CH3NH3PbX3, where X = CI, Br, and I) nanowires (NWs) with remarkable electric and optical properties have recently garnered increasing attention, owing to their structural flexibility and tunability compared to inorganic semiconducting NWs. While most recently reported NWs are limited to methylammonium/formamidinium three-dimensional lead halide perovskites, it is urgent to develop new organic inorganic hybrid semiconducting NWs. Here, broad-band-emissive single-crystal semiconductive NWs based on a new ABX(3)-type organic inorganic chain hybrid, (2-methylpiperidine)lead tribromide, are reported. It is believed that this work will enrich the organic inorganic hybrid semiconducting NWs and may provide potential applications for LED displaying.