De/rehydrogenation kinetics and reversibility of MgH2 are improved by doping with activated carbon nanofibers (ACNF) and compositing with LiBH4. Via doping with 5 wt % ACNF, hydrogen absorption of Mg to MgH2 (T = 320 degrees C and p(H-2) = 50 bar) increases from 0.3 to 4.5 wt % H-2. Significant reduction of onset dehydrogenation temperature of MgH2 to 340 degrees C (Delta T = 70 degrees C as compared with pristine MgH2) together with 6.8-8.2 wt % H-2 can be obtained by compositing Mg-5 wt. % ACNF with LiBH4 (LiBH4:Mg mole ratios of 0.5:1, 1:1, and 2:1). During dehydrogenation of Mg-rich composites (0.5:1 and 1:1 mol ratios), the formation of MgB2 and Mg0.816Li0.184 implying the reaction between LiBH4 and MgH2 favors kinetic properties and reversibility, while the composite with 2:1 mol ratio shows individual dehydrogenation of LiBH4 and MgH2. For up-scaling to hydrogen storage tank (similar to 120 times greater sample weight than laboratory scale) of the most suitable composite (1:1 mol ratio), de/rehydrogenation kinetics and hydrogen content released at all positions of the tank are comparable and approach to those from laboratory scale. Due to high purity (100%) and temperature of hydrogen gas from hydride tank, the performance of single proton exchange membrane fuel cell enhances up to 30% with respect to the results from compressed gas tank. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.