화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.42, No.38, 24256-24262, 2017
Multi-mode hydrogen storage in nanocontainers
Hydrogen can be stored in containers or in materials (in molecular or atomic forms). The atomic form can further exist as multiple phases. Molecular hydrogen can be adsorbed on the surface or can be present inside the material. By invoking multiple modes of hydrogen storage, we establish a paradigm shift in the philosophy of hydrogen storage. Using a novel strategy of storage of molecular hydrogen in metal (Pd) nanocontainers, we observe that 18% hydrogen is in molecular form. Interestingly, this is achieved at 25 degrees C and 1 atm pressure; which is in contrast to storage in MOFs and carbonaceous materials like nano tubes. Enhancement in storage capacity as compared to Pd nanocrystals of the same mass is observed (36% increase at 1 atm & 25 degrees C), along with fast kinetics (0.5 wt% hydrogen absorption in 5 s). A new mechanism for hydrogen storage involving the dual catalytic role of Pd is established. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.