Ti2Nb10O29 (TNO) microspheres are fabricated combining a solvothermal method with a subsequent heat-treatment. Structural and morphological properties of the as-prepared material have been characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption/desorption. The electro-chemical performance is evaluated by performing cyclic voltammograms and galvanostatic discharge/charge tests. The electrochemical characterization demonstrates that the as-prepared TNO microspheres exhibit a good electrochemical performance with a discharge capacity of 185 mAh g(-1) after 200 cycles and a capacity retention of 94% at 10 C. Furthermore, since TNO may react with Li at a voltage above 1.0 V vs. Li+/Li, TNO micro spheres could be the promising high-power anode materials for 2 V vs. Li+/Li lithium-ion batteries applications. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.