The study of the hydration kinetics appears as a prerequisite for understanding the physical and mechanical phenomena that control the behavior of cementitious materials. This research is based on monitoring the evolution of the degree of hydration for ordinary cement and those containing 10% of limestone powder, 20% of natural pozzolana or 30% of the blast furnace slag under high temperatures. The results provide a better understanding the effect of cure temperature on the hydration kinetics and understand the contribution of mineral additions on improving the cement properties. A new model proposed gives the satisfaction results for predicting in later age the heat of hydration of cements blended kept under constant temperatures. The latter has a wider appreciation of the results, where it gives correlation coefficients very close of unity. This justifies the reliability of this new model proposed.