The aqueous ammonia process is a promising CO2 capture technology for post-combustion flue gas treatment. The most attractive advantage of this technology is a relative low cost of solvent regeneration compared to traditional amine solutions. In this work, the absorption of CO2 into aqueous ammonia was experimentally studied in a gas/liquid contactor fitted with hollow fiber PTFE membranes at ambient temperature. The absorption performance was evaluated in terms of K(G)a(v). Experimental results indicated aqueous ammonia can absorb CO2 in a hollow fiber membrane contactor over a wide range of experimental conditions. The value of KG ranged from 1.06 x 10(-4) to 2.89 x 10(-4) m/s. The impacts of operating parameters including CO2 partial pressure, liquid flow rate, ammonia concentration and inlet CO2 solution loading were evaluated. The parametric impacts are similar to those of traditional amine-based absorption processes. Although the reactivity of aqueous ammonia is moderately lower than MEA, the K(G)a(v) value of aqueous ammonia is the same order of magnitude as that of MEA under the same operating conditions. As the liquid flow rate increases aqueous ammonia can achieve a performance comparable to MEA solvent. Long-term stability tests showed the absorption performance of aqueous ammonia remained constant in the first hour and then gradually decreased over time. Precipitation of ammonium salts was observed on the membrane surface of the shell side, which caused membrane fouling and may facilitate membrane wetting.