Journal of Physical Chemistry A, Vol.103, No.7, 823-832, 1999
Low-temperature rotational relaxation of N-2 studied with resonance-enhanced multiphoton ionization
The rotational relaxation of molecular nitrogen has been investigated down to temperatures of about 5 K with a combination of resonance-enhanced multiphoton ionization and supersonic beam time-of-flight techniques. The average rotational relaxation cross section obtained shows a maximum value of 50-60 Angstrom(2) at 20-30 K. For lower temperatures this cross section decreases and reaches a value smaller than 30 Angstrom(2) at T approximate to 5 K. For temperatures above 30 K, the cross section decreases slowly as the temperature grows and converges approximately to the determinations from other non-jet techniques and theoretical estimates available for T > 80 K. The results are compared to previous measurements from other groups using different methods, and general good agreement is found. However, we observe a significant discrepancy with some of the data from electron-beam-induced fluorescence that yield much larger cross sections for temperatures lower than 30K.
Keywords:STIMULATED RAMAN-SPECTROSCOPY;ELECTRON-IMPACT IONIZATION;SUPERSONIC FREE JETS;DIATOMIC-MOLECULES;ENERGY RELAXATION;RATE CONSTANTS;NOZZLE BEAMS;NITROGEN;TIME;FLUORESCENCE