Na2Fe2Ti6O16 freudenbergite has been synthesized using a simple solid-state route and conventionally sintered to reach 94% density ceramics. High temperature electrical and thermal transport properties have been investigated for the first time. In the temperature range of 468 K-1000 K, the electrical conductivity of Na2Fe2Ti6O16 can be well fitted with small polaron hopping model. For a further verification of the model, we measured the room-temperature optical reflectivity and derived the optical conductivity (sigma(omega)) with Kramers Kronig analysis. A mid-infrared peak in sigma(omega) confirms the presence of small polarons. From 468 K to 1000 K, Na2Fe2Ti6O16 is an n-type oxide and exhibits a temperature independent Seebeck coefficient (similar to-590 mu V K-1), in agreement with the small polaron hopping mechanism. The thermal conductivity decreases with increasing temperature from 16.5 W m(-1).K-1 (373 K) to 3.4 W m(-1).K-1 (1000 K). Na2Fe2Ti6O16 shows a maximum figure of merit (ZT) similar to 3 x 10(-4) at 1000 K. (C) 2017 Elsevier B.V. All rights reserved.