New poly(arylene ether sulfone) (PAES)-based anion-exchange membranes with side-chain aromatic benzyltrimethyl ammonium are synthesized, and their cross-linked membranes are prepared using tetramethyl alkylene diamine as a cross-linking agent. The new side-chain-type PAES-based membrane (Q) has acceptable hydroxide conductivity (sigma) of 34 mS cm(-1) (80 A degrees C) and high chemical stability in hot alkali solution. Compared with Q, the corresponding series of cross-linked membranes exhibit much higher performance, such as higher dimensional stability and chemical stability, better oxidative stability, and lower methanol permeability (P (M)). Among them, N,N,N',N'-tetramethyl-1,6-diaminohexane-based cross-linked membrane (6CQ20) with IEC of 1.29 meq g(-1) shows reasonably high sigma of 35 mS cm(-1) (80 A degrees C) and low P (M) of 0.20 x 10(-6) cm(2) s(-1), and displays high alkaline stability against alkali treatment at 60 A degrees C for 216 h with small reduction in hydroxide conductivity by only 14%.