Magnesium silicide (Mg2Si) is considered as a promising candidate among semiconducting materials for thermoelectric energy harvesting at medium functional temperature range (room temperature - 600 degrees C) due to its light weight, good thermo-physical properties and economically inexpensive. However, synthesis of pure Mg2Si compound through conventional metallurgical processes are found to be a difficult task. The present investigation reports on the simple and robust attempt to fabricate nanocrystalline Mg2Si bulk compound from mechanically milled nanostrutured Mg-Si powder mixture by self-propagating high temperature synthesis (SHS) in spark plasma sintering (SPS). X ray diffraction and trasnsmission electron microscopy (TEM) analysis confirms the phase formation and structural features of Mg2Si compound by SPS. Energy dispersive X-ray absorption spectroscopy (EDAX) mapping reveals the homogenous distribution of constituent elementals and an estimated stochiometry. Differential thermal analysis (DTA) study confirms the lowering of recrystallization and combustion temperatures of milled Mg-Si powder mixture. It is understood that SPS temperature and pressure plays a crucial role in the reaction and densification kinectics in Mg2Si formation of theoretical density. The fabricated nanocrystalline Mg2Si exhibits n type semiconducting behavior and superior power factor (thermo-power) of 11.160 mu W/cm-K-2 at 300 degrees C. (C) 2017 Elsevier B.V. All rights reserved.