Microporous metal organic framework-based copolymers with efficient gas adsorption capability and high temporal stability

Jong-Yeong Jung; Sung-Ho Ko; Su-Lim Park; Hun-Hee Shin; Hyun-Chang Oh; Jong-Wan Ryu; Seung-Chul Lee; O-Pil Kwon; Eun-Young Choi

Macromolecular Research, Vol.25, No.11, 1100-1104, November, 2017

DOI10.1007/s13233-017-5147-0 Export Citation

Microporous metal organic framework-based copolymers with efficient gas adsorption capability and high temporal stability

Jong-Yeong Jung, Sung-Ho Ko, Su-Lim Park, Hun-Hee Shin, Hyun-Chang Oh, Jong-Wan Ryu¹, Seung-Chul Lee¹, O-Pil Kwon^{1, †}, and Eun-Young Choi^†

Korea Science Academy of KAIST, 111 Baegyanggwanmun-ro, Busanjin-gu, Busan 47162, Korea
¹Department of Molecular Science and Technology, Ajou University, Suwon, Gyeonggi 16499, Korea

E-mail:,

We report new microporous metal-organic 3D coordinated copolymers that exhibit both highly efficient gas adsorption capability and high temporal stability. The Zn-coordinated copolymers (MBCn) were prepared by mixing two organic ligands at various molar ratios: the widely used benzenedicarboxylate (BDC) and its analogous Cn-acid with non-polar alkoxy side chains of various lengths. All MBCn copolymers bearing alkoxy side chains exhibited identical framework structures to that of MOF-5 prepared with only the BDC ligand. Interestingly, compared to MOF-5, MBCn copolymers exhibited up to three times higher gas adsorption properties and higher temporal structural stability. Therefore, copolymerization with organic ligands bearing alkoxy side chains is a promising strategy for the development of new microporous metal-organic hybrid materials.

Keywords:coordination polymers;copolymers;gas adsorption;metal-organic frameworks;metallopolymers

[References]

Rodriguez NA, Parra R, Grela MA, RSC Adv., 5, 73112 (2015)
Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM, Science, 341, 123044 (2013)
Zhao D, Timmons DJ, Yuan D, Zhou HC, Acc. Chem. Res., 44, 123 (2011)
Pan L, Chen Z, Deng W, Yan G, Liu X, Macromol. Res., 24(4), 366 (2016)
Wang J, Huang W, Pan L, Wang H, Zhang C, Liu X, Macromol. Res., 23(4), 309 (2015)
Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM, Science, 295, 469 (2002)
Horcajada P, Gref R, Baati T, Allan PK, Maurin G, Couvreur P, Ferey GR, Morris RE, Serre C, Chem. Rev., 112, 1232 (2011)
Gascon J, Corma A, Kapteijn F, Xamena FXLI, ACS Catal., 4, 361 (2014)
Li H, Eddaoudi M, O’Keeffe M, Yaghi OM, Nature, 402, 276 (1999)
Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM, Science, 300, 1127 (2003)
Saha D, Bao Z, Jia F, Deng S, Environ. Sci. Technol., 44, 1820 (2010)
Deng HX, Doonan CJ, Furukawa H, Ferreira RB, Towne J, Knobler CB, Wang B, Yaghi OM, Science, 327(5967), 846 (2010)
Wu T, Shen L, Luebbers M, Hu C, Chen Q, Ni Z, Masel RI, Chem. Commun., 46, 6120 (2010)
Kaye SS, Dailly A, Yaghi OM, Long JR, J. Am. Chem. Soc., 129(46), 14176 (2007)
Greathouse JA, Allendorf MD, J. Am. Chem. Soc., 128(33), 10678 (2006)
Kole GK, Vittal JJ, Chem. Soc. Rev., 42, 1755 (2012)
Low JJ, Benin AI, Jakubczak P, Abrahamian JF, Faheem SA, Willis RR, J. Am. Ceram. Soc., 131, 15834 (2009)
Choi EY, Gao C, Lee HJ, Kwon OP, Lee SH, Chem. Commun., 7563 (2009).
Rowsell JLC, Spencer EC, Eckert J, Howard JAK, Yaghi OM, Science, 309, 1350 (2005)
Chen B, Zhao X, Putkham A, Hong K, Lobkovsky EB, Hurtado EJ, Fletcher AJ, Thomas KM, J. Am. Chem. Soc., 130(20), 6411 (2008)
Thornton AW, Nairn KM, Hill JM, Hill AJ, Hill MR, J. Am. Chem. Soc., 131(30), 10662 (2009)
Li JR, Kuppler RJ, Zhou HC, Chem. Soc. Rev., 38, 1477 (2009)
Farrusseng D, Daniel C, Gaudillere C, Ravon U, Schuurman Y, Mirodatos C, Dubbeldam D, Frost H, Snurr RQ, Langmuir, 25(13), 7383 (2009)
Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM, Science, 300, 1127 (2003)

[Referenced By]

[1] Rodriguez NA, Parra R, Grela MA, RSC Adv., 5, 73112 (2015)

[2] Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM, Science, 341, 123044 (2013)

[3] Zhao D, Timmons DJ, Yuan D, Zhou HC, Acc. Chem. Res., 44, 123 (2011)

[4] Pan L, Chen Z, Deng W, Yan G, Liu X, Macromol. Res., 24(4), 366 (2016)

[5] Wang J, Huang W, Pan L, Wang H, Zhang C, Liu X, Macromol. Res., 23(4), 309 (2015)

[6] Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM, Science, 295, 469 (2002)

[7] Horcajada P, Gref R, Baati T, Allan PK, Maurin G, Couvreur P, Ferey GR, Morris RE, Serre C, Chem. Rev., 112, 1232 (2011)

[8] Gascon J, Corma A, Kapteijn F, Xamena FXLI, ACS Catal., 4, 361 (2014)

[9] Li H, Eddaoudi M, O’Keeffe M, Yaghi OM, Nature, 402, 276 (1999)

[10] Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM, Science, 300, 1127 (2003)

[11] Saha D, Bao Z, Jia F, Deng S, Environ. Sci. Technol., 44, 1820 (2010)

[12] Deng HX, Doonan CJ, Furukawa H, Ferreira RB, Towne J, Knobler CB, Wang B, Yaghi OM, Science, 327(5967), 846 (2010)

[13] Wu T, Shen L, Luebbers M, Hu C, Chen Q, Ni Z, Masel RI, Chem. Commun., 46, 6120 (2010)

[14] Kaye SS, Dailly A, Yaghi OM, Long JR, J. Am. Chem. Soc., 129(46), 14176 (2007)

[15] Greathouse JA, Allendorf MD, J. Am. Chem. Soc., 128(33), 10678 (2006)

[16] Kole GK, Vittal JJ, Chem. Soc. Rev., 42, 1755 (2012)

[17] Low JJ, Benin AI, Jakubczak P, Abrahamian JF, Faheem SA, Willis RR, J. Am. Ceram. Soc., 131, 15834 (2009)

[18] Choi EY, Gao C, Lee HJ, Kwon OP, Lee SH, Chem. Commun., 7563 (2009).

[19] Rowsell JLC, Spencer EC, Eckert J, Howard JAK, Yaghi OM, Science, 309, 1350 (2005)

[20] Chen B, Zhao X, Putkham A, Hong K, Lobkovsky EB, Hurtado EJ, Fletcher AJ, Thomas KM, J. Am. Chem. Soc., 130(20), 6411 (2008)

[21] Thornton AW, Nairn KM, Hill JM, Hill AJ, Hill MR, J. Am. Chem. Soc., 131(30), 10662 (2009)

[22] Li JR, Kuppler RJ, Zhou HC, Chem. Soc. Rev., 38, 1477 (2009)

[23] Farrusseng D, Daniel C, Gaudillere C, Ravon U, Schuurman Y, Mirodatos C, Dubbeldam D, Frost H, Snurr RQ, Langmuir, 25(13), 7383 (2009)

[24] Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM, Science, 300, 1127 (2003)