파일럿 규모에서 철-니켈 합금 에칭폐액 재생

채병만; 김대원; 황성옥; 김득현; 이상우; Byungman Chae; Dae-Weon Kim; Sung-Ok Hwang; Deukhyeon Kim; Sangwoo Lee

Clean Technology, Vol.23, No.4, 393-400, December, 2017

DOI10.7464/ksct.2017.23.4.393 Export Citation

파일럿 규모에서 철-니켈 합금 에칭폐액 재생

Recovery of Iron-Nickel Alloy Etching Waste Solution in Pilot Scale

채병만, 김대원¹, 황성옥, 김득현, 이상우

(주)케이엠씨, 39414 경북 구미시 3공단3로 40
¹고등기술연구원 신소재공정센터, 17180 경기 용인시 처인구 백암면 고안로 51번길 175-28

Byungman Chae, Dae-Weon Kim¹, Sung-Ok Hwang, Deukhyeon Kim, and Sangwoo Lee

R&D center, KMC CO., LTD, Gumi, 39414, Korea
¹Advanced Materials and Processing Center, Institute for Advanced Engineering (IAE), Yongin 17180, Korea

초록

본 연구에서는 염화제이철의 재생공정으로 기존 용매추출법에서 사용하고 있는 용매인 TBP 및 Alamine336 대신에 새로운 용매를 통해 용액 내에 존재하는 Ni과 Fe를 분리 및 회수하는 공정을 개발하였다. Lab 실험을 통하여 실험조건을 최적화하였으며, 이를 바탕으로 상업화를 위한 10 L h-1급 파일럿 설비를 구축하였다. 또한 파일럿 실험을 통하여 양산을 위한 공정 데이터를 확보하였으며, 제조된 염화제이철의 부식실험을 통하여 사용할 수 있는 제품 품질에 문제없음을 확인하였다.

In this study, we have developed a process for separating and recovering Ni and Fe in solution through a new solvent instead of TBP and Alamine336, which are solvents used in the conventional solvent extraction method. Experimental conditions were optimized through lab test and a 10 L h-1 pilot plant was constructed for commercialization. In addition, the process data for mass production were obtained through pilot experiment and it was confirmed that there is no problem in product quality that can be used through the corrosion test of ferric chloride.

Keywords:Solvent extraction;Ferric chloride solution;Regeneration;Etching;Corrosion rate

[References]

Lee KJ, M.S. Dissertation, University of Mokpo, Mokpo (2003).
Lee HM, Park M, Park GH, Park C, Korean Chem. Eng. Res., 50(2), 211 (2012)
Allen DM, Almond HJA, J. Mater. Process. Technol., 149, 238 (2004)
Allen DM, Ler LT, J. Environ. Monit., 1, 103 (1999)
Lee H, Ahn E, Park C, Tak Y, Appl. Chem. Eng., 24(1), 67 (2013)
Yoo KG, Jha MK, Kim MS, Yoo JM, Jeong JK, Lee JC, J. Korean Inst. Resour. Recycl., 17(1), 80 (2008)
Ahn JW, Yang JW, J. Korean Inst. Resour. Recycl., 6(3), 9 (1997)
Lee MS, Kim MS, J. Korean Inst. Resour. Recycl., 14(3), 48 (2005)
Lee MS, Chae JG, J. Korean Inst. Resour. Recycl., 17(5), 37 (2008)
Lee MS, Kwak YK, J. Korean Inst. Resour. Recycl., 17(3), 29 (2008)
Park M, Kim YW, Park J, Park C, Clean Technol., 13(4), 274 (2007)
Lee MS, Lee KJ, J. Korean Inst. Met. Mater., 42(2), 205 (2004)
Perry RH, Don WG, “Perry's Chemical Engineers Handbook,” McGraw-Hill Professional, 15-29 (1999).
Park IJ, Kim DW, Kim GH, Chae HJ, Lee SW, Jung HC, Clean Technol., 23(3), 279 (2017)

[Referenced By]

[1] Lee KJ, M.S. Dissertation, University of Mokpo, Mokpo (2003).

[2] Lee HM, Park M, Park GH, Park C, Korean Chem. Eng. Res., 50(2), 211 (2012)

[3] Allen DM, Almond HJA, J. Mater. Process. Technol., 149, 238 (2004)

[4] Allen DM, Ler LT, J. Environ. Monit., 1, 103 (1999)

[5] Lee H, Ahn E, Park C, Tak Y, Appl. Chem. Eng., 24(1), 67 (2013)

[6] Yoo KG, Jha MK, Kim MS, Yoo JM, Jeong JK, Lee JC, J. Korean Inst. Resour. Recycl., 17(1), 80 (2008)

[7] Ahn JW, Yang JW, J. Korean Inst. Resour. Recycl., 6(3), 9 (1997)

[8] Lee MS, Kim MS, J. Korean Inst. Resour. Recycl., 14(3), 48 (2005)

[9] Lee MS, Chae JG, J. Korean Inst. Resour. Recycl., 17(5), 37 (2008)

[10] Lee MS, Kwak YK, J. Korean Inst. Resour. Recycl., 17(3), 29 (2008)

[11] Park M, Kim YW, Park J, Park C, Clean Technol., 13(4), 274 (2007)

[12] Lee MS, Lee KJ, J. Korean Inst. Met. Mater., 42(2), 205 (2004)

[13] Perry RH, Don WG, “Perry's Chemical Engineers Handbook,” McGraw-Hill Professional, 15-29 (1999).

[14] Park IJ, Kim DW, Kim GH, Chae HJ, Lee SW, Jung HC, Clean Technol., 23(3), 279 (2017)