화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.58, 80-86, February, 2018
DOI10.1016/j.jiec.2017.09.010  Export Citation
Tailored layer-by-layer deposition of silica reinforced polyelectrolyte layers on polymer microcapsules for enhanced antioxidant cargo retention
Jin Yong Lee1, Kyounghee Shin1, Hyemin Seo1, Hwiseok Jun2, Alex Naoto Shishido Hirai3, 4, Jin Won Lee5, Yoon Sung Nam2, 6, †, and Jin Woong Kim1, 3, †
  • 1Department of Bionano Technology, Hanyang University, Ansan 15588, Republic of Korea
  • 2Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Daejeon 34141, Republic of Korea
  • 3Department of Chemical and Molecular Engineering, Hanyang University, Ansan 15588, Republic of Korea
  • 4Chemistry Institute of São Carlos, University of São Paulo, São Carlos 13560-970, Brazil
  • 5Department of Skin Science and Cosmetics, ENPRANI Co., Ltd., Incheon 22341, Republic of Korea
  • 6KAIST Institute for NanoCentury (KINC CNiT), Korea Advanced Institute of Science and Technology, Daejeon 34141, Republic of Korea
E-mail:,
This study reports a robust and straightforward approach to fabricate polymer microcapsules with a silica reinforced polyelectrolyte thin shell layer. We showed that the layer-by-layer deposition of silica nanoparticles with polyelectrolytes remarkably reinforced the shell layer, which was experimentally demonstrated by focused ion beam analysis. Moreover, we demonstrated that the molecular degradation of a model antioxidant encapsulated in our capsule system was effectively hindered during long-term storage. This indicates that the presence of the silica nanoparticles-reinforced polyelectrolyte shell layer displayed enhanced cargo retention against leakage of the antioxidant as well as oxygen attack from the surroundings.
Keywords:Polymer microcapsules;Layer-by-layer deposition;Shell reinforcement;Antioxidant cargo retention
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